ChemicalBook--->CAS DataBase List--->31126-95-1

31126-95-1

31126-95-1 Structure

31126-95-1 Structure
IdentificationBack Directory
[Name]

Rhodium(II) trifluoroacetate dimer
[CAS]

31126-95-1
[Synonyms]

Rhodium(II) trifluor
Rhodiumtrifluoroacetate
Rhodium(II) trifluoroacetate
Rhodium(I) trifluoroacetate dimer
Rhodium(Ⅱ) trifluoroacetate dimer
RHODIUM(II) TRIFLUOROACETATE DIMER
Bis-(trifluoroacetic acid rhodium salt)
Rhodium(II)trifluoroacetatedimer,min.95%
Dirhodium(II) Tetrakis(trifluoroacetate)
trifluoroacetic acid rhodium(ii) salt dimer
Rhodium(II) trifluoroacetate dimer, min. 95%
RhodiuM(II) trifluoroacetate diMer, Rh2(CF3COO)4
[Molecular Formula]

C8F12O8Rh2
[MDL Number]

MFCD00209611
[MOL File]

31126-95-1.mol
[Molecular Weight]

657.87
Chemical PropertiesBack Directory
[Appearance]

green
[solubility ]

sol MeCN, DMSO, pyridine; slightly sol dichloromethane, benzene.
[form ]

Crystalline Powder
[color ]

Green
[Stability:]

hygroscopic
[InChI]

InChI=1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
[InChIKey]

PQEXTYUESSEHKW-UHFFFAOYSA-J
[SMILES]

C(C1=O[Rh+2]234O=C(C(F)(F)F)[O-][Rh+2]2(O=C(C(F)(F)F)[O-]3)(O=C(C(F)(F)F)[O-]4)[O-]1)(F)(F)F
Hazard InformationBack Directory
[Chemical Properties]

green
[Uses]

Used in the preparation of isomerically pure α,β-unsaturated carbonyl compounds and the preparation of building blocks for one-, two-, and three-dimensional molecular solids.
[reaction suitability]

reagent type: catalyst
[Synthesis]

Rhodium(II) trifluoroacetate dimer is prepared ?from Dirhodium(II) Tetraacetate by ligand displacement in refluxing trifluoroacetic acid containing trifluoroacetic anhydride.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36-37/39
[WGK Germany ]

3
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

Rhodium(II) trifluoroacetate dimer(31126-95-1)IR
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