| Identification | More | [Name]
DIPHENYLDIFLUOROSILANE | [CAS]
312-40-3 | [Synonyms]
difluorodiphenyl-silan
DIPHENYLDIFLUOROSILANE
DIFLUORODIPHENYLSILANE
ifluoro(diphenyl)silane
Difluorodiphenylsilane97%
Diphenylsilane difluoride
Diphenyl difluorosilanegas cylinder
Benzene,1,1'-(difluorosilylene)bis- | [EINECS(EC#)]
206-226-8 | [Molecular Formula]
C12H10F2Si | [MDL Number]
MFCD00017898 | [Molecular Weight]
220.29 | [MOL File]
312-40-3.mol |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
1760 | [Hazard Note ]
Corrosive | [TSCA ]
Yes |
| Hazard Information | Back Directory | [Physical properties]
bp 246–247 °C, bp 156°C50 mmHg, bp
66–70°C0.5 mmHg; d 1.155 g cm?1. | [Uses]
A moisture insensitive equivalent of diphenyldichlorosilane that is
more reactive toward nucleophiles. Source of phenyl group in the
Hiyama coupling reaction. More stable to electrophilic aromatic
substitution than diphenyldichlorosilane.
Eaborn reported that fluorosilanes are more reactive toward organometallic reagents than the
corresponding chlorosilanes, and therefore more suited for preparation of sterically hindered organosilanes. | [Preparation]
commercially available. Readily prepared
by oxidation of diphenylsilane with CuF2, or by treatment
of diphenyldichlorosilane with HF, ZnF2, NaBF4, or
(NH4)2SiF6. Rate enhancements of the chlorine–fluorine exchange have been achieved with ultrasound and addition
of water. Diethoxydiphenylsilane and related structures are
converted to diphenyldifluorosilane with 48% HF(aq). |
|
|