| Identification | Back Directory | [Name]
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL | [CAS]
340-06-7 | [Synonyms]
(+)-PHENYL(TRIFLUOROMETHYL)CARBINOL
(S)-2,2,2-TRIFLUORO-1-PHENYL-ETHANOL
(1S)-1-Phenyl-2,2,2-trifluoroethanol
(1S)-2,2,2-Trifluoro-1-phenyl-ethanol
(S)-α-(Trifluoromethyl)benzenemethanol
(αS)-α-(Trifluoromethyl)benzenemethanol
(S)-(+)-1-PHENYL-2,2,2-TRIFLUOROETHANOL
(S)-(+)-2,2,2-TRIFLUORO-1-PHENYLETHANOL
(S)-(+)-α-(TRIFLUOROMETHYL)BENZYLALCOHOL
(s)-(+)-α-(trifluoromethyl)benzyl alcohol
(S)-2,2,2-Trifluoro-1-phenylethanol,99%e.e.
(S)-(+)-α-(Trifluoromethyl)benzylAlcohol>
(1S)-(+)-1-Phenyl-2,2,2-trifluoroethan-1-ol
Benzenemethanol, α-(trifluoromethyl)-, (αS)-
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL ALCOHOL
(alphaS)-alpha-(Trifluoromethyl)benzenemethanol
(1S)-(+)-1-Phenyl-2,2,2-trifluoroethan-1-ol 99%
(S)-(+)-alpha-(Trifluoromethyl)benzyl alcohol 99%
(S)-(+)-ALPHA-(TRIFLUOROMETHYL)BENZYL AL COHOL, 99% (97% EE/GLC)
(+)-Phenyl(trifluoromethyl)carbinol, (S)-(+)-1-Phenyl-2,2,2-trifluoroethanol | [EINECS(EC#)]
206-430-7 | [Molecular Formula]
C8H7F3O | [MDL Number]
MFCD00077845 | [MOL File]
340-06-7.mol | [Molecular Weight]
176.14 |
| Chemical Properties | Back Directory | [Boiling point ]
73-76 °C9 mm Hg(lit.)
| [density ]
1.3 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.462(lit.)
| [Fp ]
184 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Liquid | [pka]
11.91±0.10(Predicted) | [color ]
Clear colorless to pale yellow | [Optical Rotation]
[α]20/D +31.3±0.5°, neat | [BRN ]
2327547 | [InChI]
1S/C8H7F3O/c9-8(10,11)7(12)6-4-2-1-3-5-6/h1-5,7,12H/t7-/m0/s1 | [InChIKey]
VNOMEAQPOMDWSR-ZETCQYMHSA-N | [SMILES]
O[C@@H](c1ccccc1)C(F)(F)F |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
3
| [F ]
10-23 | [HS Code ]
29062990 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
(S)?-?(+)?-?α-?(Trifluoromethyl)?benzyl Alcohol is used in the synthesis of metal-organic framework compounds which may have mesoporous properties. | [Purification Methods]
Purify the chiral alcohols by fractional distillation preferably in a vacuum. [Morrison & Ridgeway Tetrahedron Lett 573 1969, NMR: Pirkle & Beare J Am Chem Soc 90 6250 1968.] The racemate [340-05-6] has b 52-54o/2mm,57-59o/2mm, 64-65o/5mm, d 4 20 1.293, n D 20 1.457, and the 2-carbobenzoyl derivative has m 137-138o [Mosher et al. J Am Chem Soc 78 4374 1956]. [Beilstein 6 IV 3043.] |
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Energy Chemical
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Sigma-Aldrich
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