ChemicalBook--->CAS DataBase List--->3425-61-4

3425-61-4

3425-61-4 Structure

3425-61-4 Structure
IdentificationBack Directory
[Name]

tert-Amyl hydroperoxide
[CAS]

3425-61-4
[Synonyms]

TAHP
1-AMYLHYDROPEROXIDE
t-amyl hydroperoxide
tert-amyl hydroperoxide
tert-Pentyl hydroperoxide
2-hydroperoxy-2-methylbutane
2-hydroperoxy-2-methyl-butane
1,1-dimethylpropyl hydroperoxide
Hydroperoxide, 1,1-dimethylpropyl
3425-61-4 tert-Amyl hydroperoxide
[EINECS(EC#)]

222-321-7
[Molecular Formula]

C5H12O2
[MDL Number]

MFCD00072658
[MOL File]

3425-61-4.mol
[Molecular Weight]

104.15
Chemical PropertiesBack Directory
[Melting point ]

-70°C
[Boiling point ]

135.3°C (rough estimate)
[density ]

0.905
[vapor pressure ]

43.2hPa at 25℃
[refractive index ]

1.5000 (estimate)
[Fp ]

41℃
[form ]

A liquid or gas
[pka]

12.71±0.50(Predicted)
[Odor]

clear water-wh. liq. or gas, sharp odor
[Water Solubility ]

63.25g/L at 20℃
[InChI]

InChI=1S/C5H12O2/c1-4-5(2,3)7-6/h6H,4H2,1-3H3
[InChIKey]

XRXANEMIFVRKLN-UHFFFAOYSA-N
[SMILES]

C(OO)(C)(C)CC
[LogP]

2.9
[EPA Substance Registry System]

tert-Amyl hydroperoxide (3425-61-4)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)Flame (GHS02)Corrosion (GHS05)Environment (GHS09)Skull and Crossbones (GHS06)
GHS08,GHS02,GHS05,GHS09,GHS06
[Signal word ]

Danger
[Hazard statements ]

H341-H331-H317-H226-H302-H314-H411-H242-H311
[Precautionary statements ]

P261-P271-P304+P340-P311-P321-P403+P233-P405-P501-P201-P202-P281-P308+P313-P405-P501-P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501
[Risk Statements ]

7-11-52/53-68
[Safety Statements ]

3/7-14-16-23-36/37/39-61
[RIDADR ]

3107
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

29096000
[Toxicity]

LD50 orl-rat: 863 mg/kg 85GMAT -,21,82
Hazard InformationBack Directory
[Uses]

tert-AmylHydroperoxide is a free radical initiator; used in preparation of low-dielectric high-strength resin compound, prepreg and laminate.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 68, p. 643, 1946 DOI: 10.1021/ja01208a034
[Flammability and Explosibility]

Flammable
[Safety Profile]

Poison by intraperitoneal route. Moderately toxic by ingestion.When heated to decomposition it emits acrid smoke and irritating fumes.
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