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75-65-0

75-65-0 Structure

75-65-0 Structure
IdentificationMore
[Name]

tert-Butanol
[CAS]

75-65-0
[Synonyms]

1,1-Dimethylethanol
1-BUTANOL
2-Methyl-2-propan0l
2-METHYL-2-PROPANOL
2-METHYLPROPAN-2-OL
AKOS BBS-00004346
ALCOHOL C4
ALCOHOL SOLVENT
ALCOHOL SOLVENT MIXED SOL'N
BUTAN-1-OL
BUTANE-1-OL
BUTANOL
BUTYLALCOHOL
BUTYL ALCOHOL, N
BUTYL ALCOHOL, NORMAL
BUTYL HYDROXIDE
FEMA 2178
HP-TBA
N-BUTANOL
N-BUTYL ALCOHOL
[EINECS(EC#)]

200-751-6
[Molecular Formula]

C4H10O
[MDL Number]

MFCD00004464
[Molecular Weight]

74.12
[MOL File]

75-65-0.mol
Chemical PropertiesBack Directory
[Appearance]

clear colourless liquid after melting
[mp ]

23-26 °C(lit.)
[bp ]

83 °C(lit.)
[density ]

0.81 g/mL at 25 °C(lit.)
[vapor density ]

2.55 (vs air)
[vapor pressure ]

31 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.399(lit.)
[Fp ]

95 °F
[storage temp. ]

2-8°C
[Stability:]

Stable. Very flammable. Incompatible with strong oxidizing agents, copper, copper alloys, alkali metals, aluminium.
[Water Solubility ]

soluble
[Merck ]

14,1542
[BRN ]

906698
[CAS DataBase Reference]

75-65-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethanol, 1,1-dimethyl-(75-65-0)
[EPA Substance Registry System]

75-65-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,F,T
[Risk Statements ]

R11:Highly Flammable.
R20:Harmful by inhalation.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S7:Keep container tightly closed .
[RIDADR ]

UN 1120 3/PG 3
[WGK Germany ]

1
[RTECS ]

EO1925000
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29051410
[Safety Profile]

Moderately toxic by ingestion, intravenous, and intraperitoneal routes. An experimental teratogen. Other experimental reproductive effects. Dangerous fire hazard when exposed to heat or flame. Moderately explosive in the form of vapor when exposed to flame. Ignites on contact with potassium-sodum alloys. To fight fire, use alcohol foam, CO2, dry chemical. Incompatible with oxidizing materials, H202. See also n-BUTYL ALCOHOL and ALCOHOLS.
[Hazardous Substances Data]

75-65-0(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Etanol-->Benzene-->ISOBUTYLENE-->1,3-BUTADIENE-->SULFATE STANDARD-->Liquefied petroleum ges-->Sodium tert-butoxide
[Preparation Products]

ETHOPERMETHRIN,95%-->(R,R)-(+)-HYDROBENZOIN-->(2-TERT-BUTOXYFORMAMIDO-PYRIDIN-4-YL)METHYL METHANESULFONATE-->5-Bromo-7-azaindole-->(2-BROMO-PYRIDIN-3-YL)-CARBAMIC ACID TERT-BUTYL ESTER-->TERT-BUTYL GLYCIDYL ETHER-->4-TERT-BUTYL-2,6-DIMETHYL BENZYL ACETATE-->tert-Butyl peroxybenzoate-->tert-Butyl acetate -->2,4-Dichlorophenoxybutyric acid-->5-TERT-BUTYL-M-XYLENE-->Dibutyl sebacate-->Di-tert-butyl peroxide-->tert-Butyl peroxypivalate -->TERT-BUTYL ISOTHIOCYANATE-->4-ALLYL-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER-->1-CHLORO-4-ISOCYANOBENZENE-->TERT-BUTYL 4-(HYDROXYMETHYL)PYRIDIN-2-YLCARBAMATE-->Butoconazole-->6-tert-Butyl-m-cresol-->2,4-DI-(TERT-BUTOXY)-5-BROMOPYRIMIDINE-->2-tert-Butyl-4,5-dichloro-3-2H-pyridazinone-->tert-Butyl peroxy-2-ethylhexanoate-->Butylparaben-->4-Tert-butyl-2,6-dimethylbenzylchloroide -->2-tert-Butyl-4-methylphenol-->5-TERT-BUTOXYCARBONYLAMINO-PYRIDINE-3-CARBOXYLIC ACID-->sodium butyl 9(or 10)-(sulphonatooxy)octadecanoate -->4-(BROMOMETHYL)-BENZOIC ACID, 1,1-DIMETHYLETHYL ESTER-->4-PIPERIDINECARBOXYLIC ACID T-BUTYL ESTER HCL-->RH-5849(Rhom & Haas-->Butyl stearate -->Dispersant CS-->2,2'-Methylenebis(6-tert-butyl-4-methylphenol)-->TERT-BUTYL 4-(METHOXYCARBONYL)PYRIDIN-2-YLCARBAMATE-->BENZYL BUTYL ETHER
Hazard InformationBack Directory
[General Description]

Colorless oily liquid with a sharp alcohol odor. Floats and mixes with water. Produces irritating vapor. Freezing point is 78°F.
[Reactivity Profile]

Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: an explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenylm-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].
[Air & Water Reactions]

Highly flammable. Water soluble.
[Hazard]

Irritant to eyes and skin. Flammable, dan- gerous fire risk. Central nervous system impair- ment. Questionable carcinogen.
[Health Hazard]

Vapor is narcotic in action and irritating to respiratory passages. Liquid is irritating to skin and eyes.
[Potential Exposure]

Butyl alcohols are used as solvents for paints, lacquers, varnishes, natural and synthetic resins, gums, vegetable oils, dyes, camphor, and alkaloids. They are also used as an intermediate in the manufacture of pharmaceuticals and chemicals; in the manufacture of artificial leather, safety glass; rubber and plastic cements, shellac, raincoats, photographic films, perfumes; and in plastic fabrication.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy
[Fire Hazard]

This chemical is flammable.
[Shipping]

UN1120 Butanols, Hazard Class: 3; Labels: 3— Flammable liquid. UN1212 Isobutanol or Isobutyl alcohol, Hazard Class: 3; Labels: 3—Flammable liquid
[Incompatibilities]

Butyl alcohols may form explosive mixture with air. In all cases they are Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some plastics, rubber and coatings. n-Butanol is incompatible with strong acids; halogens, caustics, alkali metals; aliphatic amines; isocyanates. sec-Butanol forms an explosive peroxide in air. Ignites with chromium trioxide. Incompatible with strong oxidizers; strong acids; aliphatic amines; isocyanates, organic peroxides. tert-Butanol is incompatible with strong acids (including mineral acid), including mineral acids; strong oxidizers or caustics, aliphatic amines; isocyanates, alkali metals (i.e., lithium, sodium, potassium, rubidium, cesium, francium). isoButanol is incompatible with strong acids; strong oxidizers; caustics, aliphatic amines; isocyanates, alkali metals and alkali earth. May react with aluminum at high temperatur
[Waste Disposal]

Incineration, or bury absorbed waste in an approved land fill.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

tert-Butanol(75-65-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

tert-Butanol(75-65-0) MS
tert-Butanol(75-65-0) 1H NMR
tert-Butanol(75-65-0) Raman
tert-Butanol(75-65-0) IR2
tert-Butanol(75-65-0) IR1
tert-Butanol(75-65-0) 13C NMR
tert-Butanol(75-65-0) ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

tert-Butanol, for analysis ACS(75-65-0)
[Alfa Aesar]

tert-Butyl alcohol, anhydrous, 99.8%, packaged under Argon in resealable ChemSeal™ bottles(75-65-0)
[Sigma Aldrich]

75-65-0(sigmaaldrich)
[TCI AMERICA]

tert-Butanol,>99.0%(GC)(75-65-0)
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