ChemicalBook--->CAS DataBase List--->3437-95-4

3437-95-4

3437-95-4 Structure

3437-95-4 Structure
IdentificationMore
[Name]

2-Iodothiophene
[CAS]

3437-95-4
[Synonyms]

2-IODTHIOPHENE
2-THIENYL IODIDE
2-iodo-thiophen
2-Iodothyophene
alpha-Iodothiophene
thiophene,2-iodo-
2-Iodothiophene, 98+%
2-IODOTHIOPHENE , STABILIZED WITH COPPER
2-Iodothiophene, 98%, stab. with copper
[EINECS(EC#)]

222-342-1
[Molecular Formula]

C4H3IS
[MDL Number]

MFCD00005424
[Molecular Weight]

210.04
[MOL File]

3437-95-4.mol
Chemical PropertiesBack Directory
[Appearance]

colorless to light yellow liquid
[Melting point ]

-40 °C (lit.)
[Boiling point ]

73 °C/15 mmHg (lit.)
[density ]

1.902 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.651(lit.)
[Fp ]

160 °F
[storage temp. ]

0-6°C
[form ]

Liquid
[color ]

Clear yellow-green to red-brown
[Specific Gravity]

1.902
[Sensitive ]

Light Sensitive
[BRN ]

104666
[InChI]

1S/C4H3IS/c5-4-2-1-3-6-4/h1-3H
[InChIKey]

ROIMNSWDOJCBFR-UHFFFAOYSA-N
[SMILES]

Ic1cccs1
[CAS DataBase Reference]

3437-95-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Thiophene, 2-iodo-(3437-95-4)
[EPA Substance Registry System]

3437-95-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36/37:Wear suitable protective clothing and gloves .
S27:Take off immediately all contaminated clothing .
[WGK Germany ]

3
[F ]

3
[Hazard Note ]

Irritant
[TSCA ]

T
[HazardClass ]

IRRITANT
[HS Code ]

29349990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Nitric acid-->Iodine-->Thiophene-->Mercuric Oxide-->Thiophene(SIV) (9CI)
[Preparation Products]

2-(Thien-2-yl)pyrrolidine-->2-Acetyl-5-cyanothiophene-->2-Acetyl-5-iodothiophene-->2-Chlorothiophene-->2-Thiophenecarbonyl chloride-->2-n-Butyrylthiophene-->2,5-Dibromothiophene-->1,3,5-tri(thiophen-2-yl)benzene-->3-(2-Thienyl)pyridine-->alpha-Sexithiophene-->2-n-Propylthiophene-->2,5-Diiodothiophene-->2-(Butylthio)thiophene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Iodothiophene(3437-95-4).msds
Hazard InformationBack Directory
[Chemical Properties]

colorless to light yellow liquid
[Uses]

2-Iodothiophene was used in the synthesis of (E)-and (Z)-2,3-difluoro-3-aryl substituted acrylic esters. It was also used as monomer in the preparation of thin conductive films via plasma polymerization of 2-iodothiophene.
[Synthesis Reference(s)]

Tetrahedron Letters, 36, p. 4883, 1995 DOI: 10.1016/0040-4039(95)00876-E
[General Description]

Mechanism of the fluoride-free, palladium-catalyzed cross-coupling reaction of 2-iodothiophene with potassium (E)-heptenyldimethylsilanolate has been investigated. 2-Iodothiophene participates in microwave-enhanced, rapid homogeneous-phase version of the Sonogashira reaction.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Iodothiophene(3437-95-4)1HNMR
2-Iodothiophene(3437-95-4)13CNMR
2-Iodothiophene(3437-95-4)IR1
2-Iodothiophene(3437-95-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Iodothiophene, 98+%(3437-95-4)
[Alfa Aesar]

2-Iodothiophene, 98%, stab. with copper(3437-95-4)
[Sigma Aldrich]

3437-95-4(sigmaaldrich)
[TCI AMERICA]

2-Iodothiophene,>97.0%(GC)(3437-95-4)
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