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34810-13-4

34810-13-4 Structure

34810-13-4 Structure
IdentificationMore
[Name]

9-Anthraldehyde oxime
[CAS]

34810-13-4
[Synonyms]

9-ANTHRALDEHYDE OXIME
9-ANTHRALDOXIME
AKOS B004031
9-Anthraldehyde oxime, predominantly syn
9-ANTHRALDEHYDE OXIME, 99%, PREDOMINANTL Y SYN
[EINECS(EC#)]

625-998-0
[Molecular Formula]

C15H11NO
[MDL Number]

MFCD00012252
[Molecular Weight]

221.25
[MOL File]

34810-13-4.mol
Chemical PropertiesBack Directory
[Melting point ]

162-164 °C(lit.)
[CAS DataBase Reference]

34810-13-4(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

9-Anthraldehyde oxime was used in preparation of new triosmium cluster [Os3(CO)11(C14H9CN)].
[General Description]

Gallium triflate catalyzed dehydration of 9-anthraldehyde oxime to nitrile is reported.
[Synthesis]

9-Anthraldehyde oxime was first synthesized by Hinkel and co-authors in 1935 (m.p. 186–187 °C). In repeating the preparation of the same compound by Fieser and Hartwell used a different procedure that afforded the desired compound in 93% yield with a different melting point of 165 °C.[1]
[References]

[1] S. M. Ahmed,  P. Quadrelli,  Faiq H S Hussain. “9-Anthraldehyde oxime: a synthetic tool for variable applications.” Monatshefte für Chemie - Chemical Monthly 570 1 (2020): 1643–1658.
Spectrum DetailBack Directory
[Spectrum Detail]

9-Anthraldehyde oxime(34810-13-4)1HNMR
9-Anthraldehyde oxime(34810-13-4)FT-IR
9-Anthraldehyde oxime(34810-13-4)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

34810-13-4(sigmaaldrich)
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