| Identification | More | [Name]
PERFLUORO(METHYLCYCLOHEXANE) | [CAS]
355-02-2 | [Synonyms]
FLUTEC PP2
FLUTECR PP2
PERFLUORO(METHYLCYCLOHEXANE)
TETRADECAFLUOROMETHYLCYCLOHEXANE
(TRIFLUOROMETHYL)UNDECAFLUOROCYCLOHEXANE
UNDECAFLUORO(TRIFLUOROMETHYL)CYCLOHEXANE
(Trifluormethyl)-undecafluorcyclohexan
(Trifluoromethyl)undecafluorohexane
(Trifluoromethyl)undecaflurocyclohexane
1,1,2,2,3,3,4,4,5,5,6-Undecafluoro-6-(trifluoromethyl)cyclohexane
1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro-cyclohexan
Cyclohexane, 1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro-
Cyclohexane, undecafluoro(trifluoromethyl)-
cyclohexane,tetradecafluoromethyl-
Cyclohexane,undecafluoro(trifluoromethyl)-
Perfluor-(methylcyclohexan)
Tetradecafluor-(methylcyclohexan)
undecafluoro(trifluoromethyl)-cyclohexan
PERFLUORO(METHYLCYCLOHEXANE), TECH., 90%
PERFLUOROMETHYLCYCLOHEXANE 97+% | [EINECS(EC#)]
206-573-5 | [Molecular Formula]
C7F14 | [MDL Number]
MFCD00001468 | [Molecular Weight]
350.05 | [MOL File]
355-02-2.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR LIQUID | [Melting point ]
-37 °C
| [Boiling point ]
76 °C(lit.)
| [density ]
1.80 g/mL at 20 °C
| [vapor pressure ]
14kPa at 25℃ | [refractive index ]
n17/D 1.285(lit.)
| [Fp ]
75-76°C | [storage temp. ]
Refrigerator | [solubility ]
Miscible with acetone and benzene. | [form ]
Oil | [color ]
Colourless | [Specific Gravity]
1.787 | [BRN ]
1915981 | [Dielectric constant]
1.8600000000000001 | [LogP]
666 at 25℃ | [CAS DataBase Reference]
355-02-2(CAS DataBase Reference) | [EPA Substance Registry System]
Cyclohexane, 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-6-(trifluoromethyl)- (355-02-2) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
GV7610000
| [Hazard Note ]
Irritant | [TSCA ]
T | [HS Code ]
29038900 | [Toxicity]
LCLo ihl-rat: 825 ppm/14H 11FYAN 3,90,63 |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR LIQUID | [Uses]
Perfluoro(methylcyclohexane) is used as a solvent to determine fluorophilicity of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters. It combines with chloroform and acts as an ingredient for "fluorous" biphase reactions. Furthermore, it finds application as a heat transfer agent, a dielectric fluid and a perfluorocarbon tracer. It acts as a good solvent for gases. | [General Description]
Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated. | [Safety Profile]
Mildly toxic by inhalation. When heated to decomposition it emits toxic fumes of Fí. | [Purification Methods]
Reflux it for 24hours with saturated acid KMnO4 (to oxidise and remove hydrocarbons), then neutralise, steam distil, dry with P2O5 and pass slowly through a column of dry silica gel. [Glew & Reeves J Phys Chem 60 615 1956.] It can also be purified by percolation through a 1metre neutral activated alumina column, and 1H-impurities are checked by NMR. [Beilstein 5 IV 102.] IRRITANT. |
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