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355-02-2

355-02-2 Structure

355-02-2 Structure
IdentificationMore
[Name]

PERFLUORO(METHYLCYCLOHEXANE)
[CAS]

355-02-2
[Synonyms]

FLUTEC PP2
FLUTECR PP2
PERFLUORO(METHYLCYCLOHEXANE)
TETRADECAFLUOROMETHYLCYCLOHEXANE
(TRIFLUOROMETHYL)UNDECAFLUOROCYCLOHEXANE
UNDECAFLUORO(TRIFLUOROMETHYL)CYCLOHEXANE
(Trifluormethyl)-undecafluorcyclohexan
(Trifluoromethyl)undecafluorohexane
(Trifluoromethyl)undecaflurocyclohexane
1,1,2,2,3,3,4,4,5,5,6-Undecafluoro-6-(trifluoromethyl)cyclohexane
1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro-cyclohexan
Cyclohexane, 1-trifluoromethyl-1,2,2,3,3,4,4,5,5,6,6-undecafluoro-
Cyclohexane, undecafluoro(trifluoromethyl)-
cyclohexane,tetradecafluoromethyl-
Cyclohexane,undecafluoro(trifluoromethyl)-
Perfluor-(methylcyclohexan)
Tetradecafluor-(methylcyclohexan)
undecafluoro(trifluoromethyl)-cyclohexan
PERFLUORO(METHYLCYCLOHEXANE), TECH., 90%
PERFLUOROMETHYLCYCLOHEXANE 97+%
[EINECS(EC#)]

206-573-5
[Molecular Formula]

C7F14
[MDL Number]

MFCD00001468
[Molecular Weight]

350.05
[MOL File]

355-02-2.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR LIQUID
[Melting point ]

-37 °C
[Boiling point ]

76 °C(lit.)
[density ]

1.80 g/mL at 20 °C
[vapor pressure ]

14kPa at 25℃
[refractive index ]

n17/D 1.285(lit.)
[Fp ]

75-76°C
[storage temp. ]

Refrigerator
[solubility ]

Miscible with acetone and benzene.
[form ]

Oil
[color ]

Colourless
[Specific Gravity]

1.787
[Specific Heat Capacity]

Cp(liquid):353.1J/(g·K),at 25℃
[BRN ]

1915981
[Dielectric constant]

1.8600000000000001
[Cosmetics Ingredients Functions]

BINDING
ABSORBENT
EMULSION STABILISING
SKIN CONDITIONING
ANTICAKING
[InChI]

1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
[InChIKey]

QIROQPWSJUXOJC-UHFFFAOYSA-N
[SMILES]

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
[LogP]

666 at 25℃
[CAS DataBase Reference]

355-02-2(CAS DataBase Reference)
[EPA Substance Registry System]

Cyclohexane, 1,1,2,2,3,3,4,4,5,5,6-undecafluoro-6-(trifluoromethyl)- (355-02-2)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

GV7610000
[Hazard Note ]

Irritant
[TSCA ]

T
[REACH Registrations]

Active
[HS Code ]

29038900
[Storage Class]

10 - Combustible liquids
[Toxicity]

LCLo ihl-rat: 825 ppm/14H 11FYAN 3,90,63
Hazard InformationBack Directory
[Chemical Properties]

CLEAR LIQUID
[Uses]

Perfluoro(methylcyclohexane) is used as a solvent to determine fluorophilicity of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters. It combines with chloroform and acts as an ingredient for "fluorous" biphase reactions. Furthermore, it finds application as a heat transfer agent, a dielectric fluid and a perfluorocarbon tracer. It acts as a good solvent for gases.
[General Description]

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.
[Safety Profile]

Mildly toxic by inhalation. When heated to decomposition it emits toxic fumes of Fí.
[Purification Methods]

Reflux it for 24hours with saturated acid KMnO4 (to oxidise and remove hydrocarbons), then neutralise, steam distil, dry with P2O5 and pass slowly through a column of dry silica gel. [Glew & Reeves J Phys Chem 60 615 1956.] It can also be purified by percolation through a 1metre neutral activated alumina column, and 1H-impurities are checked by NMR. [Beilstein 5 IV 102.] IRRITANT.
Spectrum DetailBack Directory
[Spectrum Detail]

PERFLUORO(METHYLCYCLOHEXANE)(355-02-2)MS
PERFLUORO(METHYLCYCLOHEXANE)(355-02-2)IR1
PERFLUORO(METHYLCYCLOHEXANE)(355-02-2)IR2
PERFLUORO(METHYLCYCLOHEXANE)(355-02-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Perfluoro(methylcyclohexane), 94%(355-02-2)
[Sigma Aldrich]

355-02-2(sigmaaldrich)
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