ChemicalBook--->CAS DataBase List--->355-42-0

355-42-0

355-42-0 Structure

355-42-0 Structure
IdentificationMore
[Name]

PERFLUOROHEXANE
[CAS]

355-42-0
[Synonyms]

FC-72
FLUORINERT
FLUORINERT FC-72
FLUORINERT(R) FC-72
FLUORINERT (TM) (FC-72) (R)
FLUTEC PP1
FLUTECR PP1
PERFLUORO-COMPOUND FC-72
PERFLUOROHEXANE
PERFLUOROHEXANES
PERFLUORO-N-HEXANE
TETRADECAFLUOROHEXANE
1,1,1,2,2,3,3,4,4,5,5,6,6,6-Tetradecafluorohexane
1,1,1,2,2,3,3,4,4,5,5,6,6,6-Tetradecafluoro-hexane
FluorinertLiquidFC72
FluorinertPF5060
Hexane, tetradecafluoro-
hexane,tetradecafluoro-
n-Tetradecafluorohexane
perfluorohexane(tetradecafluorohexane)
[EINECS(EC#)]

206-585-0
[Molecular Formula]

C6F14
[MDL Number]

MFCD00000437
[Molecular Weight]

338.04
[MOL File]

355-42-0.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

−4 °C(lit.)
[Boiling point ]

58-60 °C(lit.)
[density ]

1.669 g/mL at 25 °C(lit.)
[vapor pressure ]

26.5kPa at 25℃
[refractive index ]

n20/D 1.252(lit.)
[Fp ]

56-60°C
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

1.699
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Immiscible with water.
[Thermal Conductivity]

0.064 W/(m·K) at 25 ℃
[Merck ]

14,7157
[BRN ]

1802113
[Henry's Law Constant]

9.3×10-9 mol/(m3Pa) at 25℃, Brockbank (2013)
[Dielectric constant]

1.5700000000000001
[Cosmetics Ingredients Functions]

SOLVENT
[InChI]

1S/C6F14/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20
[InChIKey]

ZJIJAJXFLBMLCK-UHFFFAOYSA-N
[SMILES]

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
[LogP]

4.5 at 20℃ and pH7
[Surface tension]

11.91mN/m at 20°C
[CAS DataBase Reference]

355-42-0(CAS DataBase Reference)
[EPA Substance Registry System]

Perfluorohexane (355-42-0)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H412
[Precautionary statements ]

P273-P501
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

2810
[WGK Germany ]

3
[RTECS ]

MO4310000
[Hazard Note ]

Irritant
[TSCA ]

T
[REACH Registrations]

Active
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29033990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Aquatic Chronic 3
[Hazardous Substances Data]

355-42-0(Hazardous Substances Data)
Questions And Answer(Q&A)Back Directory
[Application]

Perfluorohexane uses and applications include: dispersant for lubricants, mold release agents, protective coatings; reaction media for polymerizations, purification, separation processes; solvent for removal of halogenated lubricants, oils, greases; carrier for halogenated material; for quick-cooling or freezing foods; heat-transfer fluid.
Because it is biologically inert and chemically stable, perfluorohexane has attracted attention in medicine. Like other fluorocarbons, perfluorohexane dissolves gases, including oxygen from the air, to a higher concentration than ordinary organic solvents. This effect is attributed to the weak intermolecular forces between perfluorohexane molecules, which allows "space" for gas molecules to partition into the liquid. Animals can be submerged in a bath of perfluorohexane without drowning, as there is sufficient oxygen available in the solvent to allow respiration to continue. This effect has led to the experimental use of perfluorohexane in treating burn victims, as their lungs can be filled with either perfluorohexane vapor or in extreme cases liquid perfluorohexane, allowing breathing to continue without the problems normally seen with pulmonary edema that sometimes occur when the inside of the lungs have been burnt e.g. by inhalation of hot smoke.
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
[Uses]

In the electronics industry as a coolant and test bath medium. Non-toxic, non-ozone-depleting, inert reaction medium.
[Definition]

ChEBI: Perfluorohexane is a fluoroalkane that is hexane in which all of the hydrogens have been replaced by fluorines. It has a role as a radioopaque medium and a non-polar solvent. It is a fluorocarbon, a fluoroalkane and a volatile organic compound. It derives from a hydride of a hexane.
[General Description]

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.
[Purification Methods]

Purify the fluorohexane by fractional freezing. The methods described for perfluoroheptane should be applicable here. [Beilstein 1 IV 348.]
Spectrum DetailBack Directory
[Spectrum Detail]

PERFLUOROHEXANE(355-42-0)MS
PERFLUOROHEXANE(355-42-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Perfluoro-compound FC-72?(355-42-0)
[Alfa Aesar]

Perfluorohexanes, 98+%(355-42-0)
[Sigma Aldrich]

355-42-0(sigmaaldrich)
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