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35789-03-8

35789-03-8 Structure

35789-03-8 Structure
IdentificationBack Directory
[Name]

TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&
[CAS]

35789-03-8
[Synonyms]

Gadolinium bis(trimethylsilyl)amide
GADOLINIUM TRIS(HEXAMETHYLDISILAZIDE)
TRIS(N N-BIS(TRIMETHYLSILYL)AMIDE)GADO&
Bis(trimethylsilyl)azanide,gadolinium(3+)
TrisN,N-bis(trimethylsilyl)amideügadolinium(III), 98%
[Molecular Formula]

C18H54GdN3Si6
[MDL Number]

MFCD03427091
[MOL File]

35789-03-8.mol
[Molecular Weight]

638.412
Chemical PropertiesBack Directory
[Melting point ]

67-90 °C(lit.)
[Fp ]

36 °F
[form ]

solid
[Water Solubility ]

Soluble in water.
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

Moisture Sensitive
[InChI]

1S/3C6H18NSi2.Gd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
[InChIKey]

LFWPRLGQJJEPDP-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)N([Gd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H228-H261-H314
[Precautionary statements ]

P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

11-14/15-34
[Safety Statements ]

16-26-36/37/39-43-45-7/8
[RIDADR ]

UN 3396 4.3/PG 2
[WGK Germany ]

3
[HazardClass ]

4.1
[PackingGroup ]

III
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Flam. Sol. 1
Skin Corr. 1B
Water-react 2
Hazard InformationBack Directory
[Uses]

Tris[N,N-bis(trimethylsilyl)amide]gadolinium(III) is used in many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.
[General Description]

Atomic number of base material: 64 Gadolinium
[reaction suitability]

core: gadolinium
reagent type: catalyst
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