ChemicalBook--->CAS DataBase List--->175923-07-6

175923-07-6

175923-07-6 Structure

175923-07-6 Structure
IdentificationBack Directory
[Name]

LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
[CAS]

175923-07-6
[Synonyms]

LANTHANUM TRIS(HEXAMETHYLDISILAZIDE)
LANTHANUM TRIS[BIS(TRIMETHYLSILYL)AMIDE]
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDO]LANTHANUM
Tris[N,N-bis(trimethylsilyl)amide]lanthanum(Ⅲ)
Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide]
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]LANTHANUM (III)
TrisN,N-bis(trimethylsilyl)amideülanthanum(III), 97%
Lanthanum (III) tris[N,N-bis(trimethylsiyl)amide] 99,9%
Tris(N,N-bis(trimethylsilyl)amide)lanthanum (III), 98+% (99.9%-La) (REO)
SilanaMine,1,1,1-triMethyl-N-(triMethylsilyl)-, lanthanuM(3+) salt (3:1)
[Molecular Formula]

C18H54LaN3Si6
[MDL Number]

MFCD00271009
[MOL File]

175923-07-6.mol
[Molecular Weight]

620.06
Chemical PropertiesBack Directory
[Melting point ]

149-153 °C(lit.)
[Fp ]

36 °F
[form ]

Powder
[color ]

white
[Sensitive ]

Air & Moisture Sensitive
[InChI]

1S/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
[InChIKey]

ZDYNTRMQDURVDM-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)N([La](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

11-14/15-34
[Safety Statements ]

16-26-36/37/39-43-45-7/8
[RIDADR ]

UN 3396 4.3/PG 2
[WGK Germany ]

3
[HazardClass ]

4.1
[PackingGroup ]

II
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Flam. Sol. 1
Skin Corr. 1B
Water-react 2
Questions And AnswerBack Directory
[Reactions]

  1. Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes. 
  2. Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones.
  3. Catalytic amidation of aldehydes with amines. 
Reactions of 175923-07-6
Hazard InformationBack Directory
[reaction suitability]

core: lanthanum
reagent type: catalyst
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