| Identification | More | [Name]
5-ACETYL-2-METHYLPYRIDINE | [CAS]
36357-38-7 | [Synonyms]
1-(6-methylpyridin-3-yl)ethan-1-one
1-(6-Methyl-3-pyridinyl)-ethanone
2-Methyl-5-acetylpyridine
5-Acetyl-2-picoline
Methyl 6-Methyl-3-pyridyl Ketone
NSC 27972
Ethanone, 1-(6-methyl-3-pyridinyl)- | [EINECS(EC#)]
252-995-8 | [Molecular Formula]
C8H9NO | [MDL Number]
MFCD00128113 | [Molecular Weight]
135.163 | [MOL File]
36357-38-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Pale-Yellow Oil | [Melting point ]
17.6°C | [Boiling point ]
55-56°C/Oil Pump | [density ]
1.0168 | [refractive index ]
1.5302 (estimate) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oil | [pka]
4.15±0.10(Predicted) | [color ]
Colourless to Pale Yellow | [Water Solubility ]
Partly miscible with water. | [CAS DataBase Reference]
36357-38-7(CAS DataBase Reference) | [EPA Substance Registry System]
36357-38-7(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
Pale-Yellow Oil | [Uses]
5-Acetyl-2-methylpyridine is used in the preparation of pyridine-2,5-dicarboxylic acid by using potassium permanganate as an oxidant. Further, it serves as a ligand for Suzuki coupling. | [Synthesis]
Prod.: from coal tar; along with Pyridine is obtained Picoline which is treated with Lithium and reacted with Acetic anhydride to acetylate the 2-Picolyl lithium. | [References]
[1] RSC Advances, 2013, vol. 3, # 40, p. 18544 - 18549
[2] Patent: US2012/232281, 2012, A1. Location in patent: Page/Page column 5
[3] Patent: EP2497767, 2012, A1. Location in patent: Page/Page column 8 |
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