ChemicalBook--->CAS DataBase List--->3695-77-0

3695-77-0

3695-77-0 Structure

3695-77-0 Structure
IdentificationMore
[Name]

TRIPHENYLMETHYL MERCAPTAN
[CAS]

3695-77-0
[Synonyms]

TIMTEC-BB SBB007907
TRIPHENYLMETHANETHIOL
TRIPHENYLMETHYL MERCAPTAN
TRITYL MERCAPTAN
TRITYLTHIOL
alpha,alpha-diphenyl-benzenemethanethio
alpha,alpha-diphenylbenzenemethanethiol
Benzenemethanethiol, alpha,alpha-diphenyl-
Methanethiol, triphenyl-
triphenyl-methanethio
Triphenymethyl mercaptan
alpha,alpha-diphenyl-alpha-toluenethiol
Triphenylmethanethiol~Trityl mercaptan
trityl hydrosulphide
Triphenylmethyl mercaptan,98+%
Triphenylmethanthiol
Triphenylmethyl mercaptan, Trityl mercaptan
[EINECS(EC#)]

223-020-3
[Molecular Formula]

C19H16S
[MDL Number]

MFCD00004854
[Molecular Weight]

276.4
[MOL File]

3695-77-0.mol
Chemical PropertiesBack Directory
[Appearance]

CREAM TO PALE YELLOW POWDER
[Melting point ]

104-106 °C (lit.)
[Boiling point ]

379.3°C (rough estimate)
[density ]

1.1716 (rough estimate)
[refractive index ]

1.6170 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[pka]

8.87±0.10(Predicted)
[color ]

Cream to pale yellow
[Water Solubility ]

It is insoluble in water.
[BRN ]

2113168
[InChIKey]

JQZIKLPHXXBMCA-UHFFFAOYSA-N
[CAS DataBase Reference]

3695-77-0(CAS DataBase Reference)
[EPA Substance Registry System]

Benzenemethanethiol, .alpha.,.alpha.-diphenyl- (3695-77-0)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20:Harmful by inhalation.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
[RIDADR ]

UN 3335
[WGK Germany ]

3
[RTECS ]

PB5335000
[F ]

10-13
[TSCA ]

Yes
[HS Code ]

29309090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Benzene, 1,1',1''-[[[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]thio]methylidyne]tris--->TRIPHENYLMETHANETHIOL ACETATE-->Triphenylmethanol-->Triphenylmethyl Chloride-->2,3-DIMETHYL-1,3-BUTADIENE
[Preparation Products]

Faropenem sodium hemipentahydrate-->Cyclic octaatomic sulfur-->Acetic acid, [(triphenylmethyl)thio]--->Trityl azide-->4-Tritylsulfanylbutanoic acid
Questions And AnswerBack Directory
[Description]

Triphenylmethanethiol is a kind of thiol, used as a reagent for the introduction of thiol group as well as the mild introduction of the mercapto functionality. It is a useful reagent in the synthesis of 1, 2 cis-1-thioglycoses2. It can also act as a novel rigid agent for capping gold nanoparticles3. It can be used as a precusor for simultaneous formation of Bis (Triphenylmethyl) Sulfide, Bis(Triphenylmethyl) Trisulfide, and Bis(Triphenylmethyl) Peroxide4.
[Reference]

  1. https://www.alfa.com/en/catalog/A14888/
  2. Blanc-Muasser, M., L. Vigne, and H. Driguez. "Triphenylmethanethiol. An useful reagent in the synthesis of 1,2 cis 1 -thioglycoses." Cheminform 22.24(1991):no-no.
  3. Li, Di, and J. Li. "Triphenylmethanethiol: a novel rigid capping agent for gold nanoclusters." New Journal of Chemistry 27.3(2003):498-501.
  4. Rozycka-Sokolowska, Ewa, et al. "Triphenylmethanethiol as a Precursor for the Simultaneous Formation of Bis (Triphenylmethyl) Sulfide, Bis(Triphenylmethyl) Trisulfide, and Bis(Triphenylmethyl) Peroxide: Crystal Structures and Hirshfeld Surface Analyses." Phosphorus & Sulfur & the Related Elements 188.4(2013):462-468.
Hazard InformationBack Directory
[Chemical Properties]

CREAM TO PALE YELLOW POWDER
[Uses]

Triphenylmethyl mercaptan, is used as a reagent used for the introduction of thiol group. Triphenylmethanethiol is a reagent used for the mild introduction of the mercapto functionality. It is also used as a pharmaceutical intermediate; Chemical synthesis.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 72, p. 1843, 1950 DOI: 10.1021/ja01160a512
Spectrum DetailBack Directory
[Spectrum Detail]

TRIPHENYLMETHYL MERCAPTAN(3695-77-0)1HNMR
TRIPHENYLMETHYL MERCAPTAN(3695-77-0)Raman
TRIPHENYLMETHYL MERCAPTAN(3695-77-0)FT-IR
TRIPHENYLMETHYL MERCAPTAN(3695-77-0)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Triphenylmethyl mercaptan, 98%(3695-77-0)
[Alfa Aesar]

Triphenylmethyl mercaptan, 98+%(3695-77-0)
[Sigma Aldrich]

3695-77-0(sigmaaldrich)
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