| Identification | Back Directory | [Name]
LEVOGLUCOSENONE | [CAS]
37112-31-5 | [Synonyms]
(1S,5R)-
Ccris 4274
Brn 4859778
LEVOGLUCOSENONE
Levoglucosenone min. 98%
6,8-DIOXA-BICYCLO[3.2.1]OCT-2-EN-4-ONE
2β,6β-(Epoxymethano)-2H-pyran-3(6H)-one
(1s)-8-dioxabicyclo(3.2.1)oct-2-en-4-one
6,8-Dioxabicyclo(3.2.1)oct-2-en-4-one, (1S)-
(2R,6S)-2,6-Epoxy-6,7-dihydrooxepin-3(2H)-one
6,8-Dioxabicyclo3.2.1oct-2-en-4-one, (1S,5R)-
(1S,5R)-6,8-Dioxabicyclo[3.2.1]oct-2-en-4-one
1,6-Anhydro-3,4-dideoxy-beta-D-pyranosen-2-one
(1β,5β)-6,8-Dioxabicyclo[3.2.1]octa-2-ene-4-one
(2R)-2β,6β-(Epoxymethano)-3,6-dihydro-2H-pyran-3-one
1,6-Anhydro-3,4-dideoxy-α-D-glycero-hex-3-enopyranose-2-ulose
1,6-Anhydro-3,4-dideoxy-a-D-glycero-hex-3-enopyranose-2-ulose
1,6-ANHYDRO-3,4-DIDEOXY-ALPHA-D-GLYCERO-HEX-3-ENOPYRANOSE-2-ULOSE
(1S,5R)-6,8-Dioxabicyclo[3.2.1]oct-2-en-4-one, (1S,5R)-6,8-Dioxa-4-oxobicyclo[3.2.1]oct-2-ene | [Molecular Formula]
C6H6O3 | [MDL Number]
MFCD00191664 | [MOL File]
37112-31-5.mol | [Molecular Weight]
126.11 |
| Chemical Properties | Back Directory | [Appearance]
Colourless to Yellow Oil | [alpha ]
D25 -460° (c = 1.0 in CHCl3) (Halpern, 1973); D31 -514.8° (c = 0.3 in CHCl3) (Taniguchi). | [Boiling point ]
113°C/3mmHg(lit.) | [density ]
1.329±0.06 g/cm3(Predicted) | [refractive index ]
nD25 1.5084 | [storage temp. ]
Amber Vial, -20°C Freezer, Under Inert Atmosphere | [solubility ]
Chloroform (Sparingly), DMSO (Slightly), Ethyl Acetate (Slightly) | [form ]
liquid | [color ]
Colourless to Yellow | [Merck ]
14,5465 | [Stability:]
Light Sensitive | [InChI]
InChI=1S/C6H6O3/c7-5-2-1-4-3-8-6(5)9-4/h1-2,4,6H,3H2/t4-,6+/m0/s1 | [InChIKey]
HITOXZPZGPXYHY-UJURSFKZSA-N | [SMILES]
[C@@]12([H])O[C@@]([H])(OC1)C(=O)C=C2 | [LogP]
-0.740 (est) |
| Hazard Information | Back Directory | [Chemical Properties]
Colourless to Yellow Oil | [Uses]
(-)-Form is a pyrolysis product of cellulose and cellulose-containing materials including pulp and paper waste products.
Known as a pyrolytic product of cellulose, its very useful as a chiral source for synthesizing natural products because of its highly | [Uses]
useful carbohydrate synthon | [Uses]
Chiral building block in organic synthesis. | [Definition]
ChEBI: Levoglucosenone is an anhydrohexose and a deoxyketohexose. |
| Safety Data | Back Directory | [Risk Statements ]
36 | [Safety Statements ]
26 | [WGK Germany ]
WGK 3 | [RTECS ]
JG7020000 | [HS Code ]
2932990090 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2 |
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