ChemicalBook--->CAS DataBase List--->37348-16-6

37348-16-6

37348-16-6 Structure

37348-16-6 Structure
IdentificationBack Directory
[Name]

HYDROBROMIC ACID >33% IN ACETIC ACID
[CAS]

37348-16-6
[Synonyms]

HYDROBROMIC ACID >33% IN ACETIC ACID
Acetic acid, mixt. with hydrobromic acid
Hydrogen bromide [33 wt% solution in glacial acetic acid]
Hydrogen bromide, 33 wt.% solution in acetic acid, extra pure
Hydrogen bromide, 33 wt.% solution in glacial acid, AcroSeal, pure
Hydrogen broMide, pure, 33 wt.% solution in glacial acid, AcroSeal
[EINECS(EC#)]

205-071-3
[Molecular Formula]

BrH
[MDL Number]

MFCD00011323
[MOL File]

37348-16-6.mol
[Molecular Weight]

80.9119
Chemical PropertiesBack Directory
[density ]

1.40 g/mL at 20 °C(lit.)
[Fp ]

65 °C
[solubility ]

soluble in Water
[form ]

Yellow to Brown Solution
[Water Solubility ]

Miscible with water, alcohol and organic solvents.
[Exposure limits]

ACGIH: TWA 10 ppm; STEL 15 ppm
OSHA: TWA 10 ppm(25 mg/m3)
NIOSH: IDLH 50 ppm; TWA 10 ppm(25 mg/m3); STEL 15 ppm(37 mg/m3)
[InChI]

InChI=1S/C2H4O2.BrH/c1-2(3)4;/h1H3,(H,3,4);1H
[InChIKey]

MNZMECMQTYGSOI-UHFFFAOYSA-N
[SMILES]

C(=O)(O)C.Br
Hazard InformationBack Directory
[Chemical Properties]

Clear yellow to golden colored fuming liquid
[Uses]

Hydrobromic acid is an indispensable raw material for organic intermediates, inorganic pharmaceuticals, photosensitive materials, dyes and medicines. It is also used in the production of bromine compounds. It is used as an important agent in the industrial processes of isomerization, polymerization, hydration and dehydration and esterification reactions. It plays an essential role for the extraction of mercury from the cinnebar ore.
[Reactions]

Hydrobromic acid reacts with sulfuric acid forming sulfur dioxide, bromine and water. The chemical equation is given below.
2HBr + H2SO4 → Br2 + SO2 + 2H2O
Hydrobromic acid reacts with propene undergoe addition reaction resulting in the formation of 2-Bromopropane. The chemical equation is given below.
HBr + C3H6 → C3H7Br
[Synthesis]

(1) By the direct combination of hydrogen (H2) and bromine (Br2).
(2) By the action of sodium bromide (NaBr) with dilute sulfuric acid (H2SO4).
(3) By hydrolysis of phosphorus tribromide (PBr3): PBr3 + 3H2O → H3PO3 + 3HBr
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Flame (GHS02)Corrosion (GHS05)
GHS07,GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H312-H335-H226-H314-H318
[Precautionary statements ]

P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P280-P305+P351+P338-P310-P280-P302+P352-P312-P322-P363-P501
[Hazard Codes ]

C
[Risk Statements ]

35-37
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

1
[HS Code ]

28111990
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