ChemicalBook--->CAS DataBase List--->7699-45-8

7699-45-8

7699-45-8 Structure

7699-45-8 Structure
IdentificationMore
[Name]

Zinc bromide
[CAS]

7699-45-8
[Synonyms]

ZINC BROMIDE
ZINC(II) BROMIDE
Zinc bromide (ZnBr2)
Zinc bromide anhydrous
zincbromide(znbr2)
zincdibromide
ZnBr2
ZincbromidePURATREM
Zincbromidewhitepowder
Zinc bromide hydrate
ZINC BROMIDE SOL. D20 2,5 OPTICAL GRADE FOR SHIELDED WINDOWS OF HOT CELLS
ZINC BROMIDE, 98+%
ZINC BROMIDE REAGENT GRADE >=98%
Zinc bromide, 99.999% metals basis
ZINC BROMIDE EXTRA PURE
ZINC BROMIDE, ANHYDROUS, BEADS,-10 MESH , 99.999%
ZINC BROMIDE, 99.9% (METALS BASIS)
ZINC BROMIDE (99.999%-ZN) SPECTRO
ZincBromide(Anhydrous)ForSynthesis
Zinc(II) bromide, anhydrous, 98%
[EINECS(EC#)]

231-718-4
[Molecular Formula]

Br2Zn
[MDL Number]

MFCD00011294
[Molecular Weight]

225.2
[MOL File]

7699-45-8.mol
Chemical PropertiesBack Directory
[Appearance]

Zinc bromide is an odorless white crystalline solid.
[Melting point ]

394 °C (lit.)
[Boiling point ]

~670 °C/1 atm (lit.)
[density ]

4.22
[refractive index ]

1.5452
[Fp ]

650°C
[storage temp. ]

APPROX >0°C
[solubility ]

Soluble in alcohol, ether, acetone and tetrahydrofuran.
[form ]

beads
[color ]

White to pale cream
[Specific Gravity]

4.2012?
[PH]

4 (H2O, 20℃)(saturated solution)
[Stability:]

Stable. Forms explosive mixtures with sodium and potassium. Protect from moisture.
[Water Solubility ]

soluble, 447 g/100 mL (20 ºC)
[Sensitive ]

Hygroscopic
[Merck ]

14,10129
[Uses]

Zinc bromide is a white crystalline powder prepared by dissolving zinc carbonate in hydrobromic acid. Zinc chloride (ZnCl2? is a white granular crystal made by the action of hydrochloric acid on zinc. Zinc iodide (ZnI2) is a white powder made by dissolving zinc in ionic acid. All of the zinc halides are soluble in water, alcohol, and ether. They were all used as halides for the collodion emulsion processes.
[CAS DataBase Reference]

7699-45-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Zinc dibromide(7699-45-8)
[EPA Substance Registry System]

7699-45-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,N
[Risk Statements ]

R34:Causes burns.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R50:Very Toxic to aquatic organisms.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S29:Do not empty into drains .
[RIDADR ]

UN 3260 8/PG 3
[WGK Germany ]

3
[RTECS ]

ZH1150000
[F ]

3-21
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

28275900
[Hazardous Substances Data]

7699-45-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen bromide-->ZINC-->Zinc oxide
[Preparation Products]

beta-Methyl vinyl phosphate (MAP)
Hazard InformationBack Directory
[General Description]

A white crystalline noncombustible solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. ZINC BROMIDE(7699-45-8) is used in medicine, in photography.
[Reactivity Profile]

Acidic inorganic salts, such as ZINC BROMIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
[Air & Water Reactions]

Hygroscopic. Water soluble
[Health Hazard]

Inhalation of dust may irritate nose and throat. Ingestion can cause irritation or corrosion of the alimentary tract; if large amount is swallowed and not thrown up, drowsiness and other symptoms of bromide poisoning may occur. Contact with eyes or skin causes irritation.
[Potential Exposure]

Zinc bromide is used in photography, rayon manufacturing and medicine
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Keep away from alkali metals. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, metallic sodium, or potassium. Store above 32 ℉/0℃.
[Chemical Properties]

Zinc bromide is an odorless white crystalline solid or white hygroscopic powder.
[Physical properties]

White crystalline powder; sharp metallic taste; orthorhombic structure; refractive index 1.5452; density 4.20 g/cm3; very hygroscopic; melts at 394°C; vaporizes at 650°C; highly soluble in water 447g/100 mL at 20°C; aqueous solution acidic; very soluble in alcohol, ether, and acetone; soluble in alkali hydroxides and ammonia solution.
[Preparation]

Zinc bromide is prepared by mixing barium bromide and zinc sulfate solutions. The product barium sulfate is removed by filtration and the filtrate is evaporated to obtain crystals of zinc bromide: BaBr2 + ZnSO4 → ZnBr2 + BaSO4
Zinc bromide also may be prepared by the action of zinc with hydrobromic acid followed by crystallization.
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

Heat ZnBr2 to 300o under vacuum (2x10-2 mm) for 1hour, then sublime it. [Wagenknecht & Juza Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1072 1965.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Zinc bromide(7699-45-8).msds
Questions And AnswerBack Directory
[Description]

Zinc bromide (chemical formula: ZnBr2) is an inorganic compound consisting of zinc and bromide. It is manufactured through the reaction between zinc oxide (alternatively, zinc metal) with hydrobromic acid, alternatively by the reaction between zinc metal and bromine. It is a kind of Lewis acid in organic chemistry. It can be used as the electrolyte in the zinc bromide battery. In oil and natural gas industry, its related solution can be used to displace drilling mud. Moreover, its solution can be used as a transparent shield against radiation. Finally, it can be used as a catalyst for the Stereospecific and regioselective reaction between silacyclopropanes with carbonyl compounds.
Zinc bromide
[References]

https://en.wikipedia.org/wiki/Zinc_bromide
https://www.alfa.com/en/catalog/B22510/
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Zinc bromide, anhydrous, extra pure, 98+%(7699-45-8)
[Alfa Aesar]

Zinc bromide, ultra dry, 99.999% (metals basis)(7699-45-8)
[Sigma Aldrich]

7699-45-8(sigmaaldrich)
[TCI AMERICA]

Zinc Bromide,>98.0%(T)(7699-45-8)
7699-45-8 suppliers list
Company Name: Hebei Mojin Biotechnology Co., Ltd
Tel: +86-13288715578 +86-13231137666 , +86-13231137666
Website: www.mojinchemical.com
Company Name: Hebei Jingbo New Material Technology Co., Ltd
Tel: +8619931165850 , +8619931165850
Website: www.hbjingbo.cn
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512 , +86-19937530512
Website: https://www.tianfuchem.com/
Company Name: Hangzhou FandaChem Co.,Ltd.
Tel: 008657128800458; +8615858145714 , +8615858145714
Website: http://www.fandachem.com
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: +86-0551-65418679 +86-18949832763 , +86-18949832763
Website: http://www.tnjchem.com
Company Name: career henan chemical co
Tel: +86-0371-86658258
Website: https://www.coreychem.com/
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 18871490254
Website: www.hubeijusheng.com
Company Name: Hebei Guanlang Biotechnology Co., Ltd.
Tel: +86-19930503282 , +86-19930503282
Website: https://www.chemicalbook.com/manufacturer/crovell/
Company Name: Xiamen AmoyChem Co., Ltd
Tel: +86-592-6051114 +8618959220845 , +8618959220845
Website: http://www.amoychem.com/
Company Name: Henan Xiangtong Chemical Co., Ltd.
Tel: 86-371-61312303
Website: www.hnxtchem.com
Company Name: Hubei xin bonus chemical co. LTD
Tel: 86-13657291602
Website: www.chemicalbook.com/ShowSupplierProductsList1549548/0.htm
Company Name: Shandong chuangyingchemical Co., Ltd.
Tel: 18853181302
Website: www.chemicalbook.com/ShowSupplierProductsList103425/0.htm
Company Name: Chongqing Chemdad Co., Ltd
Tel: +86-023-61398051 +8613650506873 , +8613650506873
Website: http://www.chemdad.com/
Company Name: CONIER CHEM AND PHARMA LIMITED
Tel: +8618523575427 , +8618523575427
Website: http://www.conier.com/
Company Name: Antai Fine Chemical Technology Co.,Limited
Tel: 18503026267 , 18503026267
Website: www.chemicalbook.com/ShowSupplierProductsList1980510/0.htm
Company Name: SIMAGCHEM CORP
Tel: +86-13806087780 , +86-13806087780
Website: http://www.simagchem.com/
Company Name: Hefei TNJ Chemical Industry Co.,Ltd.
Tel: 0551-65418671
Website: https://www.tnjchem.com
Company Name: Qingdao Trust Agri Chemical Co.,Ltd
Tel: +8613573296305 , +8613573296305
Website: www.qdtrustagri.com/
Tags:7699-45-8 Related Product Information
7789-60-8 1239-45-8 52374-36-4 1643-19-2 100-39-0 10035-10-6 10294-33-4 3485-62-9 7779-90-0 7789-41-5 7789-38-0 12124-97-9 7647-15-6 7785-23-1 7787-70-4 7758-02-3 10031-24-0 5970-45-6