ChemicalBook--->CAS DataBase List--->38066-16-9

38066-16-9

38066-16-9 Structure

38066-16-9 Structure
IdentificationMore
[Name]

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
[CAS]

38066-16-9
[Synonyms]

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
LABOTEST-BB LT00453966
Diethyl (phenylsulfanyl)methylphosphonate
Diethyl methylthiobenzyl phosphonate
Phosphonic acid, [(phenylthio)methyl]-, diethyl ester
Diethyl[(phenylthio)methyl]phosphonate, 97 %
[EINECS(EC#)]

253-770-7
[Molecular Formula]

C11H17O3PS
[MDL Number]

MFCD00015130
[Molecular Weight]

260.29
[MOL File]

38066-16-9.mol
Chemical PropertiesBack Directory
[Appearance]

clear light yellow liquid
[Boiling point ]

146-148 °C (0.5 mmHg)
[density ]

1.17
[refractive index ]

1.53-1.533
[Fp ]

146-148°C/0.5mm
[solubility ]

Difficult to mix.
[form ]

Liquid
[Specific Gravity]

1.174
[BRN ]

1246215
[CAS DataBase Reference]

38066-16-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[HS Code ]

2931499090
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow liquid
[Uses]

Diethyl phenylthiomethylphosphonate is used to produce Diethylphosphorylmethylphenylsulfoxid, Chemical reagents, pharmaceutical research, pharmaceutical intermediates.
[Application]

Diethyl phenylthiomethylphosphonate used for the conversion of aldehydes and ketones to vinyl sulfides, which can be hydrolyzed to yield  homologated aldehydes and ketones.
[Preparation]

The Arbuzov reaction between phenylthiomethyl chloride (Chloromethyl Phenyl Sulfide) and Triethyl  Phosphite is the most commonly used method of preparation (eq 1).
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
[Synthesis Reference(s)]

Synthesis, p. 309, 1978 DOI: 10.1055/s-1978-24736
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Diethyl phenylthiomethylphosphonate, 96%(38066-16-9)
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