| Identification | Back Directory | [Name]
LITHIUM TETRAMETHYLPIPERIDIDE | [CAS]
38227-87-1 | [Synonyms]
LTMP
LiTMP
piperidide
ithium 2,2,6,6-tetramethyL
LITHIUM TETRAMETHYLPIPERIDIDE
Lithium·2,2,6,6-tetramethylpiperidine
LithiuM 2,2,6,6-tetraMethylpiperidide
"2,2,6,6-tetramethylpiperidine lithium"
LithiuM 2,2,6,6-tetraMethylpiperidide 97%
Lithium 2,2,6,6-tetramethylpiperidin-1-ide
Piperidine, 2,2,6,6-tetramethyl-, lithium salt
2,2,6,6-Tetramethylpiperidine lithium salt (1:1)
Piperidine,2,2,6,6-tetramethyl-, lithium salt (1:1) | [EINECS(EC#)]
684-475-5 | [Molecular Formula]
C9H18LiN | [MDL Number]
MFCD00015910 | [MOL File]
38227-87-1.mol | [Molecular Weight]
147.19 |
| Hazard Information | Back Directory | [Uses]
Lithium 2,2,6,6-tetramethylpiperidide is a strong base and can be used:
- For the synthesis of enamines from terminal epoxides through trans-α-lithiated epoxide as an intermediate.
- For ortholithiation of arenes such as 1,3-bis(trifluoromethyl)benzene, 4,4-dimethyl-2-phenyl-2-oxazoline, 1,4-bis(trifluoromethyl)benzene and 1,3-dimethoxybenzene.
- In combination with Lewis donor ligand, N,N,N′,N′-tetramethylethylenediamine (TMEDA) for deprotonative metalation of methoxy-substituted arenes.{21]
|
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Domole Scientific
|
| Tel: |
13275595566 15001012717 |
| Website: |
http://www.domole.com/ |
| Company Name: |
3A Chemicals
|
| Tel: |
400-668-9898 |
| Website: |
www.3achem.com |
|