| Identification | More | [Name]
1-Trimethylsilyl-1-hexyne | [CAS]
3844-94-8 | [Synonyms]
1-HEXYN-1-YLTRIMETHYLSILANE
1-TRIMETHYLSILYL-1-HEXYNE
1-TRIMETHYSILYL-1-HEXYNE
TIMTEC-BB SBB009058
1-Trimethyl
(1-Hexynyl)trimethylsilane
1-Hexynyltrimethylsilane
Trimethyl(1-hexynyl)silane | [Molecular Formula]
C9H18Si | [MDL Number]
MFCD00075407 | [Molecular Weight]
154.32 | [MOL File]
3844-94-8.mol |
| Chemical Properties | Back Directory | [Boiling point ]
65 °C/35 mmHg (lit.) | [density ]
0.764 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.431(lit.)
| [Fp ]
99 °F
| [Specific Gravity]
0.764 | [BRN ]
1421652 | [InChI]
1S/C9H18Si/c1-5-6-7-8-9-10(2,3)4/h5-7H2,1-4H3 | [InChIKey]
SFCRJYVNDZSYCT-UHFFFAOYSA-N | [SMILES]
CCCCC#C[Si](C)(C)C | [CAS DataBase Reference]
3844-94-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1993 3/PG 3
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
3.2 | [PackingGroup ]
III | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
1-Trimethylsilyl-1-hexyne may be used in the preparation of enynes by coupling with vinyl triflates or aryl iodide using silver salt and Pd(PPh3)4 as catalyst. It may be used in the preparation of functionalised durene and isodurene derivatives. |
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