| Identification | More | [Name]
Methyl 3-methoxypropionate | [CAS]
3852-09-3 | [Synonyms]
3-METHOXYPROPIONIC ACID METHYL ESTER METHYL 3-METHOXYPROPIONATE 3-methoxy-propanoicacidmethylester 3-methoxy-propanoicacimethylester 3-methoxy-propionicacimethylester beta-methoxypropionicacid,methylester methyl3-methoxypropanoate methylbeta-methoxypropionate methylesterkyseliny3-methoxypropionove Propanoicacid,3-methoxy-,methylester Propanoicacid,3-methoxy-,methylether METHYL 3-METHOXYPROPIONATE, 99+% Methylmethoxypropanoate Methyl β-Methoxypropionate | [EINECS(EC#)]
223-358-1 | [Molecular Formula]
C5H10O3 | [MDL Number]
MFCD00059085 | [Molecular Weight]
118.13 | [MOL File]
3852-09-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Boiling point ]
142-143 °C (lit.) | [density ]
1.009 g/mL at 25 °C(lit.)
| [vapor pressure ]
9.733-15.999hPa at 20-25℃ | [refractive index ]
n20/D 1.402(lit.)
| [Fp ]
118 °F
| [storage temp. ]
Flammables area | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Specific Gravity]
1.013 (20℃) | [Water Solubility ]
428.60g/L(25 ºC) | [BRN ]
1744829 | [InChI]
InChI=1S/C5H10O3/c1-7-4-3-5(6)8-2/h3-4H2,1-2H3 | [InChIKey]
BDJSOPWXYLFTNW-UHFFFAOYSA-N | [SMILES]
C(OC)(=O)CCOC | [LogP]
0.1 | [CAS DataBase Reference]
3852-09-3(CAS DataBase Reference) | [EPA Substance Registry System]
3852-09-3(EPA Substance) |
| Questions And Answer | Back Directory | [Preparation]
In a dry reaction flask, 0.2 mL of Na₂CO₃ (0.05 M aq.) was added to a solution of ethyl acrylate (0.5 mmol) and methanol (2.0 mmol). The resulting reaction mixture was stirred at room temperature for approximately 5 hours until the olefins were completely consumed. The reaction progress was monitored by thin-layer chromatography (TLC). After the reaction was complete, the reaction mixture was extracted three times with ethyl acetate (3 x 5 mL). The combined organic layers were washed with brine (10 mL) and dried over Na₂SO₄. The organic layers were filtered to remove the drying agent, and the resulting organic solvent was concentrated under vacuum. The crude product was purified by silica gel column chromatography (eluent: PE: EtOAc = 8:1) to obtain methyl 3-methoxypropionate. |
| Safety Data | Back Directory | [Symbol(GHS) ]
  GHS02,GHS07 | [Signal word ]
Warning | [Hazard statements ]
H226-H315-H319-H335 | [Precautionary statements ]
P210-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 3272 3/PG 3
| [WGK Germany ]
3
| [RTECS ]
UF5274000
| [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HazardClass ]
3.2 | [PackingGroup ]
III | [HS Code ]
29189900 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
Methyl 3-methoxypropionate may be employed as acylation reagent for the lipase-catalyzed N-acylation of 1-phenylethanamine. It may be used in the synthesis of poly(2-hydroxylethyl 5-norbornene-2-carboxylate /t-butyl 5-norbornene-2-carboxylate /5-norbornene-2-carboxylic acid /maleic anhydride) resists. Lithographic performance of these resists was studied using ArF stepper. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 68, p. 544, 1946 DOI: 10.1021/ja01208a003 | [General Description]
Methyl 3-methoxypropionate is an ester. |
|
| Company Name: |
Jinan Hongjia Chemical Co., Ltd Gold
|
| Telephone: |
15253128188; 15253128188 |
| Website: |
https://shop1490029936258.1688.com/page/creditdetail.htm?spm=0.0.wp_pc_common_topnav_38229151.0 |
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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