| Identification | More | [Name]
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methyl morpholinium chloride | [CAS]
3945-69-5 | [Synonyms]
4-(4,6-DIMETHOXY-[1,3,5]TRIAZIN-2-YL)-4-METHYL-MORPHOLIN-4-IUM, CHLORIDE
4-(4,6-DIMETHOXY-1,3,5-TRIAZIN-2-YL)-4-METHYLMORPHOLINIUM CHLORIDE
4-(4,6-DIMETHOXY[1.3.5]TRIAZIN-2-YL)-4-METHYLMORPHOLINIUM CHLORIDE HYDRATE
4-(4,6-DIMETHOXY-1,3,5-TRIAZIN-2-YL)-4-METHYLMORPHOLINIUM CHLORIDE N-HYDRATE
4-(4,6-DIMETHOXY-1,3,5-TRIAZINE-2-YL)-4-METHYL MORPHOLINIUM CHLORIDE
DMTMM
KUNISHIMA COUPLING REAGENT
4-(4,6-DIMETHOXY-1,3,5-TRIAZIN-2-YL)-4-MEMORPHOLINIUM CL
4-(4,6-Dimethoxy-1,3,5-Triazin-2-Yl)-4-MethylmorpholiniumChloride(Dmt-Mm)
4-(4,6-Dimethoxy[1.3.5]triazin-2-yl)-4-methylmorpholinium chloride hydrate, 99+%
4-(4,6-DIMETHOXY-1,3,5-TRIAZINE-2-YL)-4-METHYL MORPHOLINIUM CHLORIDE (DMT-MM)
DMTMM 4-(4,6-DIMETHOXY-1,3,5-TRIAZIN-2-YL)-4-METHYLMORPHOLINIUM CHLORIDE
4-(4,6-DIMETHOXY-1,3,5-TRIAZIN-2-YL)-4-METHYL MORP
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-morpholinium chloride
DMTMM Cl
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride, 98+%
DMTMM 4-(4,6-DIMETHOXY[1.3.5]TRIAZIN-2-YL)-4-METHYLMORPHOLINIUM CHLORIDE HYDRATE
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride ,99%
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride hydrate, 98+%
4-4-methylmorpholinium chloride | [EINECS(EC#)]
447-230-1 | [Molecular Formula]
C10H19ClN4O4 | [MDL Number]
MFCD03093287 | [Molecular Weight]
294.74 | [MOL File]
3945-69-5.mol |
| Chemical Properties | Back Directory | [Appearance]
White powder or chunks | [Melting point ]
110-114 °C
| [Fp ]
92.5 °C | [storage temp. ]
-20°C | [solubility ]
DMSO (Slightly), Methanol (Sparingly), Water (Slightly) | [form ]
Powder or Chunks | [color ]
White | [Water Solubility ]
Soluble in water, Methanol. | [Detection Methods]
HPLC | [BRN ]
8026872 | [Stability:]
Hygroscopic | [Major Application]
peptide synthesis | [InChI]
InChI=1S/C10H17N4O3.ClH.H2O/c1-14(4-6-17-7-5-14)8-11-9(15-2)13-10(12-8)16-3;;/h4-7H2,1-3H3;1H;1H2/q+1;;/p-1 | [InChIKey]
BMTZEAOGFDXDAD-UHFFFAOYSA-M | [SMILES]
[N+]1(C)(CCOCC1)C1=NC(=NC(OC)=N1)OC.O.[Cl-] | [CAS DataBase Reference]
3945-69-5(CAS DataBase Reference) | [Storage Precautions]
Store under nitrogen;Light sensitive;Moisture sensitive |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H302-H314 | [Precautionary statements ]
P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R22:Harmful if swallowed.
R34:Causes burns.
R40:Limited evidence of a carcinogenic effect.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [REACH Registrations]
Inactive | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29349990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Acute Tox. 4 Oral
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
White powder or chunks | [Uses]
DMTMM, a conjugating agent that efficiently conjugat PnPS to Luminex microspheres without affecting the antigenicity of a broad set of PnPS. | [reaction suitability]
reaction type: Coupling Reactions | [Synthesis]
GENERAL METHODS: N-methylmorpholine (NMM, 6.0 mmol) was slowly added dropwise to a stirred solution of 2-chloro-4,6-dimethoxy-1,3,5-triazine (CDMT, 1.5 mmol) in anhydrous dichloromethane (CH2Cl2, 15 mL) under anhydrous conditions with continuous stirring for 10 min. Subsequently, Schiff base (1.0 mmol) and carboxylic acid (1.5 mmol) were added to the resulting white suspension of 4-(4,6-dimethoxytriazin-2-yl)-4-methylmorpholine hydrochloride (DMTMM salt) and the reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was washed sequentially with saturated sodium bicarbonate solution (NaHCO3, 15 mL) and brine (15 mL), dried over anhydrous sodium sulfate (Na2SO4) and subsequently concentrated under reduced pressure. The product was purified by silica gel short column chromatography (with ethyl acetate (EtOAc) as eluent) or by crystallization from 2-azetidinone (3l-m) to give the pure product 2-azetidinone (3a-k, 3n-o). | [References]
[1] Tetrahedron Letters, 1999, vol. 40, # 29, p. 5327 - 5330
[2] Tetrahedron, 1999, vol. 55, # 46, p. 13159 - 13170
[3] Tetrahedron Letters, 2010, vol. 51, # 1, p. 20 - 22
[4] Letters in Organic Chemistry, 2015, vol. 12, # 1, p. 44 - 49
[5] Tetrahedron Letters, 2002, vol. 43, # 18, p. 3323 - 3326 |
| Well-known Reagent Company Product Information | Back Directory | [Acros Organics]
4-(4,6-Dimethoxy[1.3.5]triazin-2-yl)-4-methylmorpholinium chloride hydrate, 99+%(3945-69-5) | [Alfa Aesar]
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride hydrate, 98+%(3945-69-5) | [Sigma Aldrich]
3945-69-5(sigmaaldrich) | [TCI AMERICA]
4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium Chloride,>98.0%(T)(3945-69-5) |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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