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41309-43-7

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41309-43-7 Structure

41309-43-7 Structure
IdentificationBack Directory
[Name]

2-(BROMOVINYL)TRIMETHYLSILANE
[CAS]

41309-43-7
[Synonyms]

(2-BROMOVINYL)TRIMETHYLSILANE(CIS
(E)-2-(Trimethylsilyl)vinyl bromide
[(E)-2-BroMovinyl](triMethyl)silane
(E)-(2-Bromoethenyl)trimethylsilane
(E)-(2-Bromoethenyl)trimethyl-silane
(2-BroMovinyl)triMethylsilane approx.
trans-1-Bromo-2-(trimethylsilyl)ethene
Silane, [(1E)-2-bromoethenyl]trimethyl-
(2-BROMOVINYL)TRIMETHYLSILANE(CIS+TRANS)
(2-BroMovinyl)triMethylsilane approx. 90% trans, 98%
(2-BROMOVINYL)TRIMETHYLSILANE , PRED OMINANTLY TRANS
(2-BROMOVINYL)TRIMETHYLSILANE, 98%, PRED OMINANTLY TRANS
β-(Trimethylsilyl)vinyl bromide, 1-Bromo-2-(trimethylsilyl)ethylene
[Molecular Formula]

C5H11BrSi
[MDL Number]

MFCD00040824
[MOL File]

41309-43-7.mol
[Molecular Weight]

179.13
Chemical PropertiesBack Directory
[Boiling point ]

50-51 °C52 mm Hg(lit.)
[density ]

1.167 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.466(lit.)
[Fp ]

85 °F
[storage temp. ]

2-8°C
[form ]

liquid
[Specific Gravity]

1.167
[Hydrolytic Sensitivity]

3: reacts with aqueous base
[BRN ]

1700085
[InChI]

InChI=1S/C5H11BrSi/c1-7(2,3)5-4-6/h4-5H,1-3H3/b5-4+
[InChIKey]

FKXCNOSKBLGEMQ-SNAWJCMRSA-N
[SMILES]

[Si](/C=C/Br)(C)(C)C
Questions And AnswerBack Directory
[Uses]

2-Bromovinyltrimethylsilane can be used as a pharmaceutical synthesis intermediate.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

10-36/37/38
[Safety Statements ]

26
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

10
[TSCA ]

No
[HazardClass ]

3.2
[PackingGroup ]

III
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

2-(BROMOVINYL)TRIMETHYLSILANE(41309-43-7)1HNMR
2-(BROMOVINYL)TRIMETHYLSILANE(41309-43-7)FT-IR
2-(BROMOVINYL)TRIMETHYLSILANE(41309-43-7)IR
2-(BROMOVINYL)TRIMETHYLSILANE(41309-43-7)Raman
Hazard InformationBack Directory
[Synthesis]

HBr gas was drummed into a mixture of trimethylmethylsilylacetylene (20 g, 0.2 mol) and benzoyl peroxide (145 mg, 0.6 mmol, 0.3 mol%) cooled in an ice bath for 15 min (the reaction progress was monitored by 1HNMR). The reaction mixture was diluted with et
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