| Identification | Back Directory | [Name]
BORANE-DIPHENYLPHOSPHINE COMPLEX | [CAS]
41593-58-2 | [Synonyms]
Borane diphenylphosphine
(Diphenylphosphine)borane
PHENYLPHOSPHINE BORANE COMPLEX
BORANE-DIPHENYLPHOSPHINE COMPLEX
DIPHENYLPHOSPHINE-BORANE COMPLEX
(Diphenylphosphine)trihydroboron
Borane-diphenylphosphine complex,94%
(T-4)-(Diphenylphosphine)trihydroboron
Borane-Diphenylphosphine CoMplex SynonyMs (Diphenylphosphine)trihydroboron | [Molecular Formula]
C12H14BP | [MDL Number]
MFCD00274254 | [MOL File]
41593-58-2.mol | [Molecular Weight]
200.02 |
| Chemical Properties | Back Directory | [Appearance]
white to off-white powder or crystals | [Melting point ]
47-50 °C(lit.)
| [Boiling point ]
148-150 °C10 mm Hg(lit.)
| [storage temp. ]
water-free area | [form ]
Solid | [color ]
White to off-white | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3 | [InChIKey]
XUFGOLYVDOBYLK-UHFFFAOYSA-N | [SMILES]
B.[H]P(c1ccccc1)c2ccccc2 |
| Hazard Information | Back Directory | [Chemical Properties]
white to off-white powder or crystals | [Uses]
Reactant for:
- Nucleophilic addition reactions (anion)
- Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
- Deprotonation reactions
- Catalytic coupling with alkynyl bromides
- Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
- Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
- Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Reductions
reagent type: reductant |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
15 | [Safety Statements ]
43 | [RIDADR ]
UN 2813 4.3/PG 2
| [WGK Germany ]
3
| [HazardClass ]
4.3 | [HS Code ]
29310099 | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Water-react 2 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Shanghai Uchem Inc.
|
| Telephone: |
15618758386 15618758386 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList15300/0_EN.htm |
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