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420-12-2

420-12-2 Structure

420-12-2 Structure
IdentificationMore
[Name]

ETHYLENE SULFIDE
[CAS]

420-12-2
[Synonyms]

DIMETHYLENE SULFIDE
ETHYLENE SULFIDE
THIIRANE
2,3-dihydro-thiiren
2,3-Dihydrothiirene
aethylensulfid
Ethylene episulfide
Ethylene episulphide
Ethylene sulphide
ethyleneepisulfide
ethyleneepisulphide
ethylenesulphide
Thiacyclopropane
thiiran
Thiirene, 2,3-dihydro-
epithioethane
ETHYLENE SULFIDE, STAB.
ethylene sufide
Ethylene Sulfide (stabilized with Butyl Mercaptan)
Tyyranen
[EINECS(EC#)]

206-993-9
[Molecular Formula]

C2H4S
[MDL Number]

MFCD00005159
[Molecular Weight]

60.12
[MOL File]

420-12-2.mol
Chemical PropertiesBack Directory
[Appearance]

clear colourless liquid
[Melting point ]

207-209℃
[Boiling point ]

55-56 °C (lit.)
[density ]

1.01 g/mL at 25 °C(lit.)
[vapor pressure ]

4.15 psi ( 20 °C)
[refractive index ]

n20/D 1.495(lit.)
[Fp ]

50 °F
[storage temp. ]

Freezer
[solubility ]

Chloroform (Soluble), Methanol (Sparingly)
[Water Solubility ]

Insoluble in water
[form ]

liquid
[color ]

Colorless to Almost colorless
[Stability:]

Stable at room temperature, but may have butylmercaptan added to enhance stability. Flammable.
[Specific Heat Capacity]

Cp(gas):0.88656J/(g·K),at 25℃
[BRN ]

102379
[Henry's Law Constant]

2.8×10-2 mol/(m3Pa) at 25℃, HSDB (2015)
[InChI]

1S/C2H4S/c1-2-3-1/h1-2H2
[InChIKey]

VOVUARRWDCVURC-UHFFFAOYSA-N
[SMILES]

C1CS1
[LogP]

0.556 (est)
[CAS DataBase Reference]

420-12-2(CAS DataBase Reference)
[IARC]

3 (Vol. 11, Sup 7) 1987
[EPA Substance Registry System]

Thiirane (420-12-2)
Safety DataBack Directory
[Hazard Codes ]

F,T
[Risk Statements ]

R11:Highly Flammable.
R23/25:Toxic by inhalation and if swallowed .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1992 3/PG 2
[WGK Germany ]

3
[RTECS ]

KX3500000
[F ]

10-13-23
[TSCA ]

TSCA listed
[HazardClass ]

6.1(a)
[PackingGroup ]

I
[HS Code ]

29349990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Eye Dam. 1
Flam. Liq. 2
[Safety Profile]

Poison by ingestion, intraperitoneal, and subcutaneous routes. Mddly toxic by inhalation. A skin, eye, and mucous membrane irritant. Questionable carcinogen with experimental tumorigenic data. Can react with oxidizing materials. When heated to decomposition, or on contact with acid or acid fumes, it emits highly toxic fumes of SOx. See also SULFIDES.
[Hazardous Substances Data]

420-12-2(Hazardous Substances Data)
Hazard InformationBack Directory
[Chemical Properties]

clear colourless liquid
[Uses]

  • Ethylene sulfide is generally used in the preparation of organosulfur compounds, especially for mercaptoethylation of primary and secondary amines to obtain aminothiols.
  • It is used in the synthesis of dendritic thioether ligands to stabilize gold nanoparticles (Au NPs).
  • Chitosan can be chemically modified by treating ethylene sulfide to obtain a biopolymer for the removal of divalent cations from aqueous solutions.

[Definition]

ChEBI:Thiirane is a saturated organic heteromonocyclic parent and an organosulfur heterocyclic compound.
Spectrum DetailBack Directory
[Spectrum Detail]

ETHYLENE SULFIDE(420-12-2)MS
ETHYLENE SULFIDE(420-12-2)1HNMR
ETHYLENE SULFIDE(420-12-2)13CNMR
ETHYLENE SULFIDE(420-12-2)IR1
ETHYLENE SULFIDE(420-12-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

420-12-2(sigmaaldrich)
[TCI AMERICA]

Ethylene Sulfide  (stabilized with Butyl Mercaptan),>98.0%(GC)(420-12-2)
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