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42189-56-0

42189-56-0 Structure

42189-56-0 Structure
IdentificationMore
[Name]

N-(1-PYRENYL)MALEIMIDE
[CAS]

42189-56-0
[Synonyms]

N-(1-PYRENE)MALEIMIDE
N-(1-PYRENYL)MALEIMIDE
N-[3-PYRENYL]MALEIMIDE
n-(3-pyrene)maleimide
1-(pyren-1-yl)-1H-pyrrole-2,5-dione
N-(1-PYRENYL)MALEIMIDE, FOR FLUOR-ESCENC E
N-(1-Pyrenyl)maleinimide
N-(1-Pyrenyl)maleimide,97%
1-(1-Pyrenyl)-1H-pyrrole-2,5-dione
1-(1-Pyrenyl)-3-pyrroline-2,5-dione
N-(Pyren-1-yl)maleimide
Pyrene maleimide
[EINECS(EC#)]

255-702-1
[Molecular Formula]

C20H11NO2
[MDL Number]

MFCD00049301
[Molecular Weight]

297.31
[MOL File]

42189-56-0.mol
Chemical PropertiesBack Directory
[Appearance]

Yellow Solid
[Melting point ]

235-237 °C(lit.)
[Boiling point ]

438.82°C (rough estimate)
[density ]

1.2310 (rough estimate)
[refractive index ]

1.5180 (estimate)
[storage temp. ]

Refrigerator
[solubility ]

Soluble in chloroform, N,Ndimethylformamide, dimethyl sulfoxide, ethanol, methanol
[form ]

Solid
[pka]

–1.21±0.20, most basic, temperature: 25°C
[color ]

Yellow needles;Gold needles
[Usage]

A fluorescent sulfhydryl reagent that can form excited-state dimers which emit at longer wavelenghts than the lone excited fluorophore.
[λmax]

338nm, 325nm (MeOH)
[BRN ]

1542661
[Biological Applications]

Analyzing molecular aspects of muscle contraction; detecting nucleic acids, proteins; determining/evaluating cell activity; diagnosing/treating Parkinson’s disease; monitoring/studying ribosomal structure and conformation; studying nicotinic acetylcholine receptor (AChR) structure; sulfhydryl reagent
[Major Application]

Dendrimers; dye functionalized single-wall carbon nanotube (SWNT) conjugated polymer devices; photovoltaic cells; polymer-coated gold electrodes; fluorescent polymers; radio-fluorogenic gel; in sequencecontrolled polymerizations; rubber
[InChI]

1S/C20H11NO2/c22-17-10-11-18(23)21(17)16-9-7-14-5-4-12-2-1-3-13-6-8-15(16)20(14)19(12)13/h1-11H
[InChIKey]

YXKWRQLPBHVBRP-UHFFFAOYSA-N
[SMILES]

O=C1C=CC(=O)N1c2ccc3ccc4cccc5ccc2c3c45
[CAS DataBase Reference]

42189-56-0(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

1
[F ]

8-10-21
[HS Code ]

29251900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Description]

Pyrene is a fluorescent hydrocarbon which emits in blue region. This is a maleimide derivative of pyrenebutyric acid which reacts with thiols.


Pyrene is a useful proximity probe because two pyrene residues close to each other exhibit strong excimer fluorescence.

[Chemical Properties]

N-(1-PYRENYL)MALEIMIDE is Yellow Solid
[Uses]

A fluorescent sulfhydryl reagent that can form excited-state dimers which emit at longer wavelenghts than the lone excited fluorophore.
[Uses]

N-(1-PYRENYL)MALEIMIDE is a fluorescent sulfhydryl reagent that can form excited-state dimers which emit at longer wavelenghts than the lone excited fluorophore.
[Uses]

Reactant used in synthesis of: • ;Oligodeoxynucleotide derivatives1 • ;Polymer conjugates of immunogenic peptides2 • ;Modified oligonucleotides for biosensing applications3,Reactant: • ;Involved in synthesis of thermally stable fluorescent maleimide/isobutene alternating copolymers4• ;Used as derivitizing agent for determination of glutathione disulfide levels in biological samples5
[Abs/Em Maxima]

343; 326; 313; 276; 265; 242; 234/377; 397 nm
Spectrum DetailBack Directory
[Spectrum Detail]

N-(1-PYRENYL)MALEIMIDE(42189-56-0)1HNMR
N-(1-PYRENYL)MALEIMIDE(42189-56-0)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

42189-56-0(sigmaaldrich)
[TCI AMERICA]

N-(1-Pyrenyl)maleimide,>97.0%(LC)(42189-56-0)
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