ChemicalBook--->CAS DataBase List--->42273-76-7

42273-76-7

42273-76-7 Structure

42273-76-7 Structure
IdentificationBack Directory
[Name]

VINYLBENZYL ALCOHOL
[CAS]

42273-76-7
[Synonyms]

AURORA KA-7349
VINYLBENZYL ALCOHOL
α-Vinylbenzyl alcohol
ALPHA-VINYLBENZYL ALCOHOL
alpha-Vinylbenzyl alcohol 97%
Fluoxetine intermediate FXT-2a
VINYLBENZYL ALCOHOL ISO 9001:2015 REACH
[Molecular Formula]

C9H10O
[MDL Number]

MFCD00093987
[MOL File]

42273-76-7.mol
[Molecular Weight]

134.18
Chemical PropertiesBack Directory
[Boiling point ]

101-102 °C/12 mmHg (lit.)
[density ]

1.021 g/mL at 25 °C (lit.)
[refractive index ]

n20/D 1.54(lit.)
[Fp ]

202 °F
[form ]

liquid
[InChI]

1S/C9H10O/c1-2-9(10)8-6-4-3-5-7-8/h2-7,9-10H,1H2
[InChIKey]

MHHJQVRGRPHIMR-UHFFFAOYSA-N
[SMILES]

OC(C=C)c1ccccc1
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

α?Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.
[Uses]

α-Vinylbenzyl alcohol may be used in the synthesis of cinnamyl ethers by reacting with alcohols.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 52, p. 3524, 1987 DOI: 10.1021/jo00392a006
[General Description]

α-Vinylbenzyl alcohol is an allyl alcohol derivative. Its isomerization reaction using a novel ternary catalyst system has been reported. The kinetic resolution of racemic α-vinylbenzyl alcohol by tungsten-catalyzed asymmetric epoxidation method has been repoorted. The coupling reaction of α-vinylbenzyl alcohol and aldehydes in the presence of RuCl2(PPh3)3 catalyst and In(OAc)3 as a co-catalyst in ionic liquids has been investigated. Etherification reaction of glycerol with α-vinylbenzyl alcohol in the presence of sulfonic catalyst immobilized on silica (SiO2–SO3H) has been reported.
Spectrum DetailBack Directory
[Spectrum Detail]

VINYLBENZYL ALCOHOL(42273-76-7)FT-IR
VINYLBENZYL ALCOHOL(42273-76-7)IR
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