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42774-15-2

42774-15-2 Structure

42774-15-2 Structure
IdentificationBack Directory
[Name]

N,N'-Bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-benzenedicarboxamide
[CAS]

42774-15-2
[Synonyms]

NYST:S-EED
Nylostab S-Eed
JADEWIN PA 612
Polyamide Stabilizer
Light stabilizer 438
Light stabilizer SEED
UV STABILIZER TRUELICHT UV 66
N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)isophthalamide
N,N'-Bis(2,2,6,6-tetramethyl-4-piperidinyl)isophthalamide
N1,N3-Bis(2,2,6,6-tetramethylpiperidin-4-yl)isophthalamide
1,3-Benzenedicarboxamide,N,N'-bis(2,2,6,6-tetramethyl-4-piperdinyl)
1,3-Benzendicarboxamide,N,N'-Bis(2,2,6,6-Tetramethyl-4-Piperidinyl)
N,N''-BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDINYL)-1,3-BENZENEDICARBOXAMIDE
1,3-Benzenedicarboxamide, N,N-bis(2,2,6,6-tetramethyl-4-piperidinyl)-
N1,N3-Bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-benzenedicarboxamide
1,3-Benzenedicarboxamide, N1,N3-bis(2,2,6,6-tetramethyl-4-p iperidinyl)-
[EINECS(EC#)]

419-710-0
[Molecular Formula]

C26H42N4O2
[MDL Number]

MFCD09751152
[MOL File]

42774-15-2.mol
[Molecular Weight]

442.64
Chemical PropertiesBack Directory
[Melting point ]

>270°C (dec.)
[Boiling point ]

605.1±55.0 °C(Predicted)
[density ]

1.09±0.1 g/cm3(Predicted)
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly, Heated)
[form ]

Solid
[pka]

13.67±0.60(Predicted)
[color ]

White to Off-White
[Water Solubility ]

139mg/L at 30℃
[InChIKey]

OYNOCRWQLLIRON-UHFFFAOYSA-N
[SMILES]

C1(C(NC2CC(C)(C)NC(C)(C)C2)=O)=CC=CC(C(NC2CC(C)(C)NC(C)(C)C2)=O)=C1
[LogP]

1.12 at 20℃
[EPA Substance Registry System]

1,3-Benzenedicarboxamide, N,N'-bis(2,2,6,6-tetramethyl- 4-piperidinyl)-(42774-15-2)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[Hazard Codes ]

Xn
[Risk Statements ]

22-36
[Safety Statements ]

22-25-26
[TSCA ]

TSCA listed
[REACH Registrations]

Active
Hazard InformationBack Directory
[Uses]

(1) N,N'-Bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-benzenedicarboxamide can be used to improve nylon melt stability, thereby improving nylon processability, reducing fiber breakage rate, and improving product quality.
(2) It has a long-term stabilizing effect on light, heat, oxidation, etc., and can improve the dispersibility of fillers and pigments in nylon.
(3) Improve pigment tinting strength, improve pigment stability, and enhance the dyeability of nylon fibers.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

Triacetonediamine

36768-62-4

Isophthaloyl dichloride

99-63-8

N,N'-Bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-benzenedicarboxamide

42774-15-2

An electric stirrer, reflux condenser and thermometer were assembled in each of the four reaction bottles. To each reaction vial was added 20.3 g of m-toluene dicarbonyl chloride, 36 g of 2,2,6,6-tetramethylpiperidinamine, 60 g of solvent, and 1.5 g of catalyst. the stirrer was started, heated to 110 °C and started to time, and the reaction time ranged from 4.5 to 10 hours. Upon completion of the reaction, the reaction mixture was slowly added to an alkaline aqueous solution under strong stirring to remove unreacted isophthaloyl chloride. Subsequently, the mixture was cooled to 15-20°C to promote crystallization. The crystallized product was collected by filtration to afford N1,N3-bis(2,2,6,6-tetramethylpiperidin-4-yl)isophthalamide. The light stabilizer had a yield of 97.38% and a melting point of 270-275 °C.

[References]

[1] Patent: CN105481759, 2016, A. Location in patent: Paragraph 0015
[2] Patent: WO2004/16591, 2004, A1. Location in patent: Page/Page column 6-7
[3] Patent: CN103554009, 2016, B. Location in patent: Paragraph 0045; 0046
[4] Patent: WO2004/16591, 2004, A1. Location in patent: Page/Page column 7-8
[5] Patent: US2018/194727, 2018, A1. Location in patent: Paragraph 0081; 0082
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