| Identification | Back Directory | [Name]
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE | [CAS]
442905-33-1 | [Synonyms]
(R)-Xyl-P-Phos
(R)-XYLYL-P-PHOS
(S)-XYLYL-P-PHOS
CTH-(R)-XYLYL-P-PHOS
CTH-(S)-XYLYL-P-PHOS
min.cth-(r)-xylyl-p-phos
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS&
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(3R)-4,4'-Bis[bis(3,5-dimethylphenyl)phosphino]-2,2',6,6'-tetramethoxy-3,3'-bipyridine
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine,min.95%CTH-(R)-Xylyl-P-Phos
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine Application:Asymmetric hydrogenation Store N2Ar | [Molecular Formula]
C46H50N2O4P2 | [MDL Number]
MFCD04974235 | [MOL File]
442905-33-1.mol | [Molecular Weight]
756.85 |
| Chemical Properties | Back Directory | [Appearance]
White solid | [Melting point ]
190-194°C | [Boiling point ]
791.1±60.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [pka]
-1.76±0.38(Predicted) | [color ]
white to pale yellow | [Optical Rotation]
[α]20/D +125°, c = 1 in chloroform | [Water Solubility ]
Sparingly soluble in water. | [InChIKey]
JRTHAKOHBMETRC-UHFFFAOYSA-N | [SMILES]
COc1cc(P(c2cc(C)cc(C)c2)c3cc(C)cc(C)c3)c(c(OC)n1)-c4c(OC)nc(OC)cc4P(c5cc(C)cc(C)c5)c6cc(C)cc(C)c6 |
| Hazard Information | Back Directory | [Chemical Properties]
White solid | [Uses]
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine is used in asymmetric hydrogenation.It acts as a ligand used in the asymmetic hydrogenation of β-keto esters, 2-arylacrylates, aryl ketones , and other substrates. Other applications include it is used widely as a Catalyst, when combined with Rh, Ru and Ir precursor. |
| Questions And Answer | Back Directory | [Reactions]
- Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.
- Chiral ligand for iridium-catalyzed asymmetric hydrogenation of quinolines.
- Chiral ligand for copper- catalyzed asymmetric hydrosilylation of ketones.
- Synthesis of new chiral 2-functionized-1,2,3,4-tetrahydroquinoline derivatives via asymmetric hydrogenation of substituted quinolines.
- Rhodium-biphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives.
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