443-09-4

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443-09-4 Structure

Identification	More
[Name] 5'-FLUORO-2'-HYDROXYPROPIOPHENONE
[CAS] 443-09-4
[Synonyms] 1-(5-Fluoro-2-hydroxyphenyl) 2-hydroxy-5-fluoropropiophenone 5'-FLUORO-2'-HYDROXYPROPIOPHENONE 1-(5-FLUORO-2-HYDROXYPHENYL)PROPAN-1-ONE 1-Propanone,1-(5-fluoro-2-hydroxyphenyl)- JRH-01109, 1-(5-Fluoro-2-hydroxyphenyl)propan-1-one, 97%
[Molecular Formula] C9H9FO2
[MDL Number] MFCD00218583
[Molecular Weight] 168.16
[MOL File] 443-09-4.mol

Chemical Properties	Back Directory
[Melting point ] 35-39 °C
[Boiling point ] 117-121 °C(Press: 22 Torr)
[density ] 1.200±0.06 g/cm3(Predicted)
[Fp ] 219 °F
[form ] solid
[pka] 8.26±0.48(Predicted)
[InChI] 1S/C9H9FO2/c1-2-8(11)7-5-6(10)3-4-9(7)12/h3-5,12H,2H2,1H3
[InChIKey] OLVYYKLFIUGMCW-UHFFFAOYSA-N
[SMILES] CCC(=O)c1cc(F)ccc1O
[CAS DataBase Reference] 443-09-4(CAS DataBase Reference)

Safety Data	Back Directory
[Hazard Codes ] Xn,Xi
[Risk Statements ] R22:Harmful if swallowed. R37/38:Irritating to respiratory system and skin . R41:Risk of serious damage to eyes.
[Safety Statements ] S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S39:Wear eye/face protection .
[WGK Germany ] 3
[Hazard Note ] Irritant
[HS Code ] 2914790090
[Storage Class] 11 - Combustible Solids
[Hazard Classifications] Acute Tox. 4 Oral Eye Dam. 1 Skin Irrit. 2 STOT SE 3

Hazard Information	Back Directory
[Preparation] Preparation by Fries rearrangement of p-fluorophenyl propionate (b.p.18–20 118–120°) with aluminium chloride at 150° for 1 h (80–81%) or at reflux for 30 min (57%) Also obtained by demethylation of 5-fluoro-2-methoxy-propiophenone (b.p.13 132°) with refluxing pyridinium chloride for 15 min (76%).

Well-known Reagent Company Product Information	Back Directory
[Sigma Aldrich] 443-09-4(sigmaaldrich)

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