ChemicalBook--->CAS DataBase List--->478980-03-9

478980-03-9

478980-03-9 Structure

478980-03-9 Structure
IdentificationBack Directory
[Name]

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
[CAS]

478980-03-9
[Synonyms]

Umicore CX21
PALLADIUM(II)
(NHC)Pd(allyl)Cl
imidazol-2-ylidene]palladium(II)
UMicore CX21, 18% Pd, Product of UMicore
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)
Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium
ALLYLCHLORO[1,3-BIS-(DIISOPROPYLPHENYL)-IMIDAZOLE-2-YLIDENE]PALLADIUM(II)
Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) 98%
ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
allyl(1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)palladium(IV) chloride
[Molecular Formula]

C30H41ClN2Pd
[MDL Number]

MFCD08561131
[MOL File]

478980-03-9.mol
[Molecular Weight]

571.53
Chemical PropertiesBack Directory
[Melting point ]

190°C (dec.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

Powder
[color ]

white
Hazard InformationBack Directory
[Chemical Properties]

Yellow crystal
[Uses]

Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.
[General Description]

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39-36/37
[WGK Germany ]

3
[HS Code ]

28439000
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for the cross-coupling of aryl chlorides with boronic acids.
  2. Catalyst for the diamination of conjugated dienes and trienes.
  3. Catalyst for the dehalogenation of aryl chlorides.
  4. Catalyst for anaerobic alcohol oxidation.
  5. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation. 
Reactions of 478980-03-9
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