| Identification | More | [Name]
TETRAPHENYLCYCLOPENTADIENONE | [CAS]
479-33-4 | [Synonyms]
2,3,4,5-TETRAPHENYL-2,4-CYCLOPENTADIEN-1-ONE
RARECHEM AM UF S096
TC
TETRACYCLONE
TETRAPHENYLCYCLOPENTADIENONE
2,3,4,5-Tetraphenyl-2,4-cyclopentadienone
2,3,4,5-tetraphenyl-4-cyclopentadien-1-one
2,3,4,5-Tetraphenylcyclopentadienone
2,4-Cyclopentadien-1-one, 2,3,4,5-tetraphenyl-
Cyclone
Cyclone (compound)
Tetracyclon
Tetracyclone-tetraphenylcyclopentadienone
Tetraphenyl-2,4-cyclopentadien-1-one
Tetraphenylcyclopentadienone,>98%
Tetraphenylcylcopentadienone
1,2,3,4-Tetraphenyl-1,3-cyclopentadiene-5-one
2,3,4,5-Tetraphenylcyclopenta-2,4-diene-1-one
Tetraphenyl-2,4-cyclopentadiene-1-one | [EINECS(EC#)]
207-530-3 | [Molecular Formula]
C29H20O | [MDL Number]
MFCD00001407 | [Molecular Weight]
384.47 | [MOL File]
479-33-4.mol |
| Chemical Properties | Back Directory | [Appearance]
crystalline purple solid | [Melting point ]
217-220 °C (lit.) | [Boiling point ]
471.14°C (rough estimate) | [density ]
1.0511 (rough estimate) | [refractive index ]
1.6020 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
Fine Crystalline Powder | [color ]
Black | [Stability:]
Stable. Combustible. Light sensitive. | [Water Solubility ]
Soluble in Benzene. Insoluble in water. | [BRN ]
683115 | [InChI]
1S/C29H20O/c30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24/h1-20H | [InChIKey]
PLGPSDNOLCVGSS-UHFFFAOYSA-N | [SMILES]
O=C1C(c2ccccc2)=C(c3ccccc3)C(c4ccccc4)=C1c5ccccc5 | [CAS DataBase Reference]
479-33-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Tetraphenylcyclopentadienone(479-33-4) | [EPA Substance Registry System]
479-33-4(EPA Substance) |
| Safety Data | Back Directory | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [TSCA ]
Yes | [HS Code ]
29143990 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
crystalline purple solid | [Uses]
Tetraphenylcyclopentadienone is a building block for several organic and organometallic compounds. It is also used as an efficient cyclone system or in re-circulation systems for the capturing of fine active pharmaceuticals and food ingredients. | [Definition]
ChEBI: Tetraphenylcyclopentadienone is a stilbenoid. | [Preparation]
Tetraphenylcyclopentadienone can be synthesized by a double aldol condensation involving benzil and dibenzyl ketone in the presence of a basic catalyst.
Tetraphenylcyclopentadienone has been prepared by the action of phenylmagnesium bromide on benzaldiphenylmaleide, and by reduction, dehydration, and oxidation of the methylenedesoxybenzoin obtained by condensing formaldehyde with desoxybenzoin. The present procedure is essentially that of Dilthey.
Synthesis of tetraphenylcyclopentadienone | [Agricultural Uses]
Tetraphenylcyclopentadienone is a dust-collecting device consisting of a cylindrical chamber, the lower portion of which is tapered to fit into a cone-shaped receptacle below it, is called a cyclone. Dust-laden air enters through a vertical slot-like duct on the upper wall of the chamber at the rate of at least 30meters a second. Since the particles enter at a tangent, they whirl in a circular or cyclonic path within the chamber. The centrifugal force exerted on the particles is proportional to their weight and square of their velocity. The particles slide along the walls of the chamber and gradually circulate down into the conical receptor, while the clean air escapes through a central pipe at the bottom. The dust accumulates in the cone and is discharged continuously or at intervals. The larger the particles, the more efficient the process of their removal. In simple cyclones, particles below 50microns in diameter are not retained, but improved models retain particles as small as 20microns.
Cyclones are used in handling and granulating fertilizers to avoid air pollution and are a safety requirement in the production plants.
| [Synthesis]
1,3-Diarylpropane-2-1 (0.3 mmol, 1 aliquot), benzylbenzene (0.3 mmol, 1 aliquot), and sodium ethoxyhydrogen ester (0.6 mmol, 2 aliquots) were mixed in ethanol (10 mL). The reaction mixture was refluxed for 5 minutes. The reaction mixture was cooled to room temperature in an ice bath. Crystals were collected by vacuum filtration. The reaction mixture was washed twice with ice-cold ethanol. The deep purple product was recrystallized from a 1:1 mixture of 95% ethanol and toluene to give Tetraphenylcyclopentadienone. |
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Energy Chemical
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Modachem Shanghai Co., Ltd
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