ChemicalBook--->CAS DataBase List--->4832-52-4

4832-52-4

4832-52-4 Structure

4832-52-4 Structure
IdentificationBack Directory
[Name]

TRIPHENYL TRITHIOORTHOFORMATE
[CAS]

4832-52-4
[Synonyms]

Tris(phenylthio)
TRIS(PHENYLTHIO)METHANE
Tris(phenylthio)methane 98%
TRIPHENYL TRITHIOORTHOFORMATE
Methanetriyltris(phenyl sulfide)
Methylidynetris(thio)trisbenzene
[Bis(phenylthio)methylthio]benzene
Benzene, 1,1,1-methylidynetris(thio)tris-
[Molecular Formula]

C19H16S3
[MDL Number]

MFCD00010396
[MOL File]

4832-52-4.mol
[Molecular Weight]

340.53
Chemical PropertiesBack Directory
[Melting point ]

39-41 °C(lit.)
[Boiling point ]

488.1±25.0 °C(Predicted)
[density ]

1.26±0.1 g/cm3(Predicted)
[Fp ]

>230 °F
[form ]

powder to crystal
[pka]

23(at 25℃)
[color ]

White to Almost white
[BRN ]

1914230
[InChI]

InChI=1S/C19H16S3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15,19H
[InChIKey]

YOQHDHPBEXTHCP-UHFFFAOYSA-N
[SMILES]

C(SC1=CC=CC=C1)(SC1=CC=CC=C1)SC1=CC=CC=C1
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[RIDADR ]

UN 3335
[WGK Germany ]

3
[F ]

13
[HS Code ]

29309090
Hazard InformationBack Directory
[Uses]

Tris(phenylthio)methane has been used in the preparation of:
  • 1-phenylthio-tetrahydroisoquinolines via activated Pictet-Spengler cyclization
  • homoallylchalcogenoacetals via reaction with allylsilanes in the presence of a Lewis acid
[storage]

Tris(phenylthio)Methane ?is stable indefinitely if stored at ambient temperatures in tightly sealed containers to exclude moisture, which promotes hydrolysis to thiophenol and formic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)MS
TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)1HNMR
TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)13CNMR
TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)IR1
TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)IR2
TRIPHENYL TRITHIOORTHOFORMATE(4832-52-4)Raman
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