ChemicalBook--->CAS DataBase List--->4891-38-7

4891-38-7

4891-38-7 Structure

4891-38-7 Structure
IdentificationMore
[Name]

METHYL PHENYLPROPIOLATE
[CAS]

4891-38-7
[Synonyms]

METHYL 3-PHENYLPROPIOLATE
METHYL-(PHENYLPROPIOLAT)
METHYL PHENYLPROPIOLATE
PHENYLPROPIOLIC ACID METHYL ESTER
2-Phenyl-1-carbomethoxyacetylene
2-Propynoic acid, 3-phenyl-, methyl ester
Methyl 3-phenyl-2-propynoate
Methyl 3-phenylpropynoate
Methyl phenylacetylenecarboxylate
Methyl phenylethynecarboxylate
Methyl phenylpropynoate
methylphenylpropynoate
Propiolic acid, 3-phenyl-, methyl ester
Propiolic acid, phenyl-, methyl ester
Methylphenylpropiolate,98+%
3-Phenyl-2-propynoicacidmethylester
3-Phenylpropargylic acid methyl ester
3-Phenylpropiolic acid methyl
Benzenepropiolic acid methyl ester
Phenylpropiolic acid methyl
[Molecular Formula]

C10H8O2
[MDL Number]

MFCD00041685
[Molecular Weight]

160.17
[MOL File]

4891-38-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to pale yellow liquid
[Melting point ]

26°C
[Boiling point ]

109-112 °C/2 mmHg (lit.)
[density ]

1.086 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.5590(lit.)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Liquid After Melting
[color ]

Clear colorless to pale yellow
[BRN ]

472813
[InChIKey]

JFGWPXKGINUNDH-UHFFFAOYSA-N
[CAS DataBase Reference]

4891-38-7(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HS Code ]

29163900
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to pale yellow liquid
[Uses]

Methyl phenylpropiolate may be used in the synthesis of:
  • bicyclohexadienes
  • cis-methyl cinnamate
  • (E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 52, p. 4859, 1987 DOI: 10.1021/jo00231a007
Tetrahedron Letters, 21, p. 849, 1980 DOI: 10.1016/S0040-4039(00)71522-X
[General Description]

Organoiron carbonyl complexes are obtained by reacting methyl phenylpropiolate with Fe2(CO)9.
Spectrum DetailBack Directory
[Spectrum Detail]

METHYL PHENYLPROPIOLATE(4891-38-7)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl phenylpropiolate, 98%(4891-38-7)
[Alfa Aesar]

Methyl phenylpropiolate, 98+%(4891-38-7)
[Sigma Aldrich]

4891-38-7(sigmaaldrich)
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