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515-74-2

515-74-2 Structure

515-74-2 Structure
IdentificationMore
[Name]

4-Amino-benzenesulfonic acid monosodium salt
[CAS]

515-74-2
[Synonyms]

4-AMINOBENZENESULFONIC ACID SODIUM SALT
4-SULFOANILINE SODIUM SALT
P-ANILINESULFONIC ACID SODIUM SALT
SODIUM ANILINESULFONATE
SODIUM SULFANILATE
SULFANILIC ACID SODIUM SALT
SULPHANILIC ACID SODIUM SALT
4-amino-benzenesulfonicacimonosodiumsalt
Benzenesulfonicacid,4-amino-,monosodiumsalt
p-Aminobenzenesulfonicacidsodiumsalt
Sodium,4-aminobenzenesulfonate
sodium4-aminobenzenesulfonate
Sodiump-aminobenzenesulfonate
sodiumsulphanilate
sulphate p-aminobenzensulfonate
SODIUM-P-AMINOBENZENSULFONATE
SULFANILICACIDSODIUMSALT,REAGENT
4-AMPYRONE 99% HIGH GRADE
4-Amino-benzenesulfonic acid monosodium salt
4-Aminobenzenesulfonic acid sodium
[EINECS(EC#)]

208-208-5
[Molecular Formula]

C6H6NNaO3S
[MDL Number]

MFCD00064394
[Molecular Weight]

195.17
[MOL File]

515-74-2.mol
Chemical PropertiesBack Directory
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Solid
[color ]

Off-white to brown
[Cosmetics Ingredients Functions]

HAIR DYEING
ANTIOXIDANT
[InChI]

InChI=1S/C6H7NO3S.Na.H/c7-5-1-3-6(4-2-5)11(8,9)10;;/h1-4H,7H2,(H,8,9,10);;
[InChIKey]

SKPUWZMHPCQXPO-UHFFFAOYSA-N
[SMILES]

S(C1C=CC(N)=CC=1)(O)(=O)=O.[NaH]
[CAS DataBase Reference]

515-74-2(CAS DataBase Reference)
[EPA Substance Registry System]

515-74-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[TSCA ]

TSCA listed
[REACH Registrations]

Active
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Sodium carbonate-->Aniline-->Sulfanilic acid-->Sulfamic acid monosodium salt-->Methyl Orange-->N,N-Diethyl-1,4-phenylenediamine
[Preparation Products]

Tartrazine-->whitener WG for wool-->4-Hydrazinobenzenesulfonic acid-->Fluorescent Brightener BC-->resist H-->Acid Orange 7-->Acid yellow 17-->REACTIVE GREEN 19-->Reactive Dark Blue M-2ge-->Mordant Yellow 10-->New red-->p-Diazobenzenesulfonic acid-->C.I. Solvent Brown 39-->Direct Brown 78-->Solvent Orange 39-->sodium p-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]benzenesulphonate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Amino-benzenesulfonic acid monosodium salt(515-74-2).msds
Questions And AnswerBack Directory
[Preparation method]

4-Amino-benzenesulfonic acid monosodium salt is obtained by transposition and neutralization of aniline sulfonated.
	4-Amino-benzenesulfonic acid monosodium salt
[Production process flow chart]

Put 98% sulphuric acid in the oil bath sulfonated cauldron and add 99% aniline to it after stirring the sulphuric acid for 1 hour. Raise the temperature of the cauldron to 160℃. Launch the vacuum system and make the vacuum degree0.053MPa in the cauldron.Then the temperature of the cauldron is raised to 200℃. The heat preservation lasts for half an hour before the temperature is raised to 260℃ and the completion of heat preservation to transposition. At this time cool and close the vacuum system, keep 10 minutes and discharge the vacuum in the cauldron, gradually cooling to 80℃ . Add water and stir it before putting in the storage tank. In the storage tank, the material is heated to 70-80 degrees centigrade. Add the sodium carbonate and neutralize it to pH=7.0 - 7.5 before moving into the neutralization cauldron with the batch mother liquid. The relative density of water is adjusted to 1.12 before being heated to boiling. Then the activated carbon will be added and stirring is made for half an hour followed by the thermal filtration. The filter cake is washed with water, and the filtrate is steamed to a relative density of 1.18. Afterwards, it is put into the crystallizer and cooled to 30 ℃ in 8 hours followed by the centrifuge filtration. The filtrate can be used as the next batch of mother liquid and the filter cake is p-aminophenylsulfonic acid.
Production process flow chart
[Uses]

4-Amino-benzenesulfonic acid monosodium salt can be used as a fungicide. It is mainly used to control the rust of wheat and the rust of other crops.It can also be used for the prevention and control of wheat rust, dilute the original fungicide with 250 times of liquid to spray the occurrence of the disease points and range. 
Spectrum DetailBack Directory
[Spectrum Detail]

4-Amino-benzenesulfonic acid monosodium salt(515-74-2)1HNMR
4-Amino-benzenesulfonic acid monosodium salt(515-74-2)13CNMR
4-Amino-benzenesulfonic acid monosodium salt(515-74-2)IR1
4-Amino-benzenesulfonic acid monosodium salt(515-74-2)IR2
Hazard InformationBack Directory
[Flammability and Explosibility]

Nonflammable
[Purification Methods]

It crystallises from water. [Beilstein 14 IV 2655.]
[References]

[1] Mills PC, et, al. Effects of inflammation-associated acute-phase response on hepatic and renal indices in the horse. Aust Vet J. 1998 Mar;76(3):187-94. DOI:10.1111/j.1751-0813.1998.tb10126.x
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