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5158-46-3

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5158-46-3 Structure

5158-46-3 Structure
IdentificationBack Directory
[Name]

METHYLZINC CHLORIDE
[CAS]

5158-46-3
[Synonyms]

Chloro(Methyl)Zinc
METHYLZINC CHLORIDE
Methylzinc(II) chloride
methylzinc chloride solution
Methylzinc chloride solution 2.0 in THF
Methylzinc chloride solution 2.0 M in THF
METHYLZINC CHLORIDE SOLUTION, ~2 M IN TH F
Methylzinc chloride, 2M solution in THF, AcroSeal
METHYLZINC CHLORIDE, 2M SOLUTION IN TETR AHYDROFURAN
Methylzinc chloride, 2M solution in THF, AcroSeal&trade
[Molecular Formula]

CH3ClZn
[MDL Number]

MFCD00192334
[MOL File]

5158-46-3.mol
[Molecular Weight]

115.88
Chemical PropertiesBack Directory
[Boiling point ]

67 °C
[density ]

1.033 g/mL at 25 °C
[Fp ]

−18 °F
[form ]

Turbid Solution
[color ]

Colorless to light yellow
[BRN ]

969141
[InChI]

1S/CH3.ClH.Zn/h1H3;1H;/q;;+1/p-1
[InChIKey]

ASUSLKVOTPUROZ-UHFFFAOYSA-M
[SMILES]

C[Zn]Cl
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H302-H314-H335-H351
[Precautionary statements ]

P210-P260-P280-P305+P351+P338-P370+P378-P403+P235
[Hazard Codes ]

F,Xi,C
[Risk Statements ]

11-19-36/37/38-40-37-34
[Safety Statements ]

16-26-36/37/39-45
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

1
[F ]

10-21
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Uses]

Methylzinc chloride can be used in:
  • Ni-catalyzed one-pot Negishi coupling with amino-heteroaryl chlorides.
  • Cross-coupling with aryl fluorides in the presence of a nickel catalyst.
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