| Identification | Back Directory | [Name]
(2β,5α,12β,19α)-4β-(Acetyloxy)-6,7-didehydro-3β-hydroxy-1-methylaspidospermidine-3-carboxylic acid methyl ester | [CAS]
5231-60-7 | [Synonyms]
Vindolidin
Vindorosin
Vindorosine
Vindolidine
Demethoxyvindoline
4-acetoxy-3-hydroxy-1-methyl-6,7-didehydro-aspidospermidine-3-carboxylic acid methyl ester
(2β,5α,12β,19α)-4β-(Acetyloxy)-6,7-didehydro-3β-hydroxy-1-methylaspidospermidine-3-carboxylic acid methyl ester
Aspidospermidine-3-carboxylic acid, 4-(acetyloxy)-6,7-didehydro-3-hydroxy-1-methyl-, methyl ester, (2β,3β,4β,5α,12R,19α)-
1H-Indolizino(8,1-cd)carbazole-5-carboxylicacid,3a-ethyl-3a,4,5,5a,6,11,12,13a-octahydro-4,5-dihydroxy-6-methyl-,methylester,4-acetate | [Molecular Formula]
C24H30N2O5 | [MDL Number]
MFCD01747117 | [MOL File]
5231-60-7.mol | [Molecular Weight]
426.51 |
| Chemical Properties | Back Directory | [Melting point ]
167° | [alpha ]
D16 -31° (chloroform) | [Boiling point ]
532.8±50.0 °C(Predicted) | [density ]
1.32±0.1 g/cm3(Predicted) | [pka]
11.49±0.60(Predicted) |
| Hazard Information | Back Directory | [Description]
An imidazolidinocarbazole alkaloid present in Vinca rosea L., the base is best crystallized from a mixture of C6H6 and light petroleum. It yields colourless
needles and has [α]16D - 31 ° (CHCl3). The ultraviolet spectrum consists of two absorption maxima occurring at 250 and 302 mμ. | [Uses]
Vindorosine is an alkaloid from Catharanthus trichophyllus Roots. Vindorosine relaxes renal arteries[1][2]. | [References]
Moza, Trojanek., Chern. & Ind., 1425 (1962)
Moza, Trojanek., Collect. Czech. Chern. Cornrnun., 28, 1419, 1427 (1963)
Synthesis:
Buchi, Matsumoto, Nishimura.']. A mer. Chern. Soc., 93, 3299 (1971) |
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