ChemicalBook--->CAS DataBase List--->5614-37-9

5614-37-9

5614-37-9 Structure

5614-37-9 Structure
IdentificationBack Directory
[Name]

Cyclopentyl methyl ether
[CAS]

5614-37-9
[Synonyms]

CPME
CMPE
METHOXYCYCLOPENTANE
Cyclopentane,methoxy-
Cyclpentyl methyl ether
CYCLOPENTYL METHYL ETHER
Methoxycyclopentane 
BARIUM 1000 MG/L IN WATER
Cyclopentyl Methyl Ether CPME
Cyclopentyl methyl ether, 99.9+%
CR2K2O7 LINEARITY SET (RSPEC1022)
Cyclopentyl methyl ether, stabilized
CYCLOPENTYL METHYL ETHER, WITH STABILIZER
Methoxycyclopentane (stabilized with BHT)
CYCLOPENTYL METHYL ETHER, 99+%, STABILIZED
Cyclopentyl methyl ether, stabilized, 99+%
Cyclopentyl methyl ether, anhydrous, >=99.9%
Cyclopentyl Methyl ether, stabilized, extra pure
Cyclopentyl methyl ether, ReagentPlus(R), >=99.90%
Cyclopentyl methyl ether,99.5%,Extra Dry,stabilized
Cyclopentyl methyl ether Vetec(TM) reagent grade, 99%
Cyclopentyl methyl ether, stabilized, extra pure, 99+%
Cyclopentyl Methyl ether, 99+%, extra pure, stabilized
Cyclopentyl methyl ether, stabilized, AcroSeal, Extra Dry
Cyclopentyl methyl ether, stabilized, AcroSeal, Extra Dry, 99.5%
Cyclopentyl Methyl ether, 99.5%, Extra Dry, stabilized, AcroSeal
Cyclopentyl methyl ether contains 50 ppm BHT as inhibitor, anhydrous, >=99.9%
Cyclopentyl methyl ether contains 50 ppm BHT as inhibitor, ReagentPlus(R), >=99.90%
Cyclopentyl Methyl ether, 98%, SpcDry, stabilized with BHT, Water≤50 ppM (by K.F.), SpcSeal
[EINECS(EC#)]

445-090-6
[Molecular Formula]

C6H12O
[MDL Number]

MFCD08276401
[MOL File]

5614-37-9.mol
[Molecular Weight]

100.16
Chemical PropertiesBack Directory
[Appearance]

clear liquid
[Melting point ]

-140°C
[Boiling point ]

106°C
[density ]

0.86
[vapor pressure ]

59.9 hPa (25 °C)
[Fp ]

106°C
[refractive index ]

1.4210
[storage temp. ]

Flammables area
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

Liquid
[color ]

APHA: ≤10
[explosive limit]

1.10-9.90%
[Water Solubility ]

Miscible with water, alcohols, ketones and hydrocarbons.
[Stability:]

Volatile
[InChI]

1S/C6H12O/c1-7-6-4-2-3-5-6/h6H,2-5H2,1H3
[InChIKey]

SKTCDJAMAYNROS-UHFFFAOYSA-N
[SMILES]

COC1CCCC1
[LogP]

1.6 at 20℃
[EPA Substance Registry System]

Cyclopentane, methoxy-(5614-37-9)
Hazard InformationBack Directory
[Chemical Properties]

Clear liquid
[Uses]

Cyclopentyl methyl ether (CPME) is an alternative to ether solvents such as THF, diethyl ether, and MTBE with a higher resistance to peroxide formation. The more environmentally conservative CPME solvent replaces hazardous solvents in order to achieve sustainability and reduce environmental and operational costs. CPME offers considerable potential and advantage as a direct replacement for CH2Cl2 in binary eluents using MeOH as the modifier with MeOH-DMC and i-PrOH-EtOAc.
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Cyclopentyl methyl ether (CPME) is a greener alternative to other ethereal solvents such as tetrahydrofuran (THF), 2-methyl tetrahydrofuran (2-MeTHF), dioxane (carcinogenic), tert-Butyl methyl ether (MTBE), and 1,2-dimethoxyethane (DME) and thus has been enhanced for "Safer Solvents and Auxiliaries". Click here for more information.
[Flammability and Explosibility]

Highlyflammable
[Synthesis]

Cyclopentyl methyl ether can be obtained by etherification reaction of refined cyclopentene mixed with methanol and heated and gasified through a fixed bed of strongly acidic cation exchange resin.

Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H302-H315-H319
[Precautionary statements ]

P210-P233-P240-P301+P312-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-22-36/38
[Safety Statements ]

26
[RIDADR ]

UN3271
[WGK Germany ]

3
[Autoignition Temperature]

180 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

2909 20 00
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
[Toxicity]

LD50 orally in Rabbit: 200 - 2000 mg/kg LD50 dermal Rat > 2000 mg/kg
Questions And AnswerBack Directory
[Overview]

Cyclopentyl methyl ether (CPME), also known as methoxycyclopentane, is new environmentally friendly hydrophobic ether solvent with high performance, and could replace tetrahydrofuran, methyl tetrahydrofuran, methyl tert-butyl ether and dioxane and other ether solvents. As a reaction solvent, it can be used for reaction such as Grignard reaction, coupling reaction, coupling amination reaction, metal reduction reaction, Lewis acid reaction and Fried-Clark reaction, etc. It is also used for extraction, crystallization, surface treatment and polymerization processes.
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