ChemicalBook--->CAS DataBase List--->56706-10-6

56706-10-6

56706-10-6 Structure

56706-10-6 Structure
IdentificationMore
[Name]

Bis(triethoxysilylpropyl) disulfide
[CAS]

56706-10-6
[Synonyms]

BIS[3-(TRIETHOXYSILYL)PROPYL]-DISULFIDE
BIS(TRIETHOXYSILYLPROPYL)DISULFIDE
4,4,13,13-tetraethoxy-3,14-dioxa-8,9-dithia-4,13-disilahexadecane
4,4,,-Tetraethoxy-3,-dioxa-8,9-dithia-4,-disilahexadecan
Bis(3-triethoxysilylpropyl)disulfane
Silane coupler SG-Si996
[Dithiobis(trimethylene)]bis(triethoxysilane)
A-1589
Bis[3-(triethoxysilyl)propyl] perdisulfide
Bis[3-(triethoxysilyl)propyl] persulfide
Y-15026
[EINECS(EC#)]

260-350-7
[Molecular Formula]

C18H42O6S2Si2
[MDL Number]

MFCD05663903
[Molecular Weight]

474.82
[MOL File]

56706-10-6.mol
Chemical PropertiesBack Directory
[Appearance]

Yellowish clear liquid
[Melting point ]

°C
[Boiling point ]

250
[density ]

1.03
[vapor pressure ]

0-7910Pa at 20-25℃
[refractive index ]

1.457
[Fp ]

75°C
[storage temp. ]

Sealed in dry,2-8°C
[Specific Gravity]

1.03
[Water Solubility ]

14-1000000000μg/L at 20℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[InChI]

InChI=1S/C18H42O6S2Si2/c1-7-19-27(20-8-2,21-9-3)17-13-15-25-26-16-14-18-28(22-10-4,23-11-5)24-12-6/h7-18H2,1-6H3
[InChIKey]

FBBATURSCRIBHN-UHFFFAOYSA-N
[SMILES]

CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC
[LogP]

-3-5.2 at 20℃
[CAS DataBase Reference]

56706-10-6(CAS DataBase Reference)
[EPA Substance Registry System]

56706-10-6(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H312-H319-H315-H332-H335
[Precautionary statements ]

P261-P271-P304+P340-P312-P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P280-P302+P352-P312-P322-P363-P501-P264-P280-P305+P351+P338-P337+P313P
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[TSCA ]

Yes
[REACH Registrations]

Active
Hazard InformationBack Directory
[Chemical Properties]

Yellowish clear liquid
[Flammability and Explosibility]

Notclassified
[Synthesis]

3-Chloropropyltriethoxysilane

5089-70-3

3-Mercaptopropyltriethoxysilane

14814-09-6

triethoxy-[3-(3-triethoxysilylpropylsulfanyl)propyl]silane

60764-86-5

Bis(triethoxysilylpropyl) disulfide

56706-10-6

General procedure for the synthesis of (3-mercaptopropyl)triethoxysilane (MPTES), compounds (CAS:60764-86-5) and bis-[3-(triethoxysilyl)propyl]-disulfide (TESPD) from 3-chloropropyltriethoxysilane (CPTES): during the reaction, 50 wt.% NaHSO4 was added drop-wise to a NaHS solution solution. 325 g (2.69 mol) of NaHS solution with 8.2 g (0.0124 mol) of tetrabutylammonium bromide (TBAB) solution were added to a glass reactor, mixed well and heated to 75 °C. Subsequently, NaHSO4 solution was added slowly and dropwise just before the imminent addition. Next, CPTES was added. 497.8 g (2.07 moles) of CPTES was added to the reaction mixture within 8 min. the addition of NaHSO4 solution needed to be completed within 30 min. After 5 hours of reaction, the organic phase was separated and analyzed by gas chromatography (GC). The analysis showed that the product contained 2.0% wt. of CPTES, 87.6% wt. of MPTES, 2.7% wt. of TESPM, and 0.7% wt. of TESPD.Finally, the product was distilled under vacuum to yield MPTES with a purity of 95.4%, which is about 84% yield based on the amount of CPTES used.

[References]

[1] Patent: US6680398, 2004, B1. Location in patent: Page column 10-11
[2] Patent: US6680398, 2004, B1. Location in patent: Page column 8-9
[3] Patent: US6680398, 2004, B1. Location in patent: Page column 10
[4] Patent: US6680398, 2004, B1. Location in patent: Page column 9-10
[5] Patent: US6680398, 2004, B1. Location in patent: Page column 9
Questions And AnswerBack Directory
[Application]

Footwear
- Abrasion resistance
- Cutting and chunking resistance
- Flex life improvement
Rolls
- Abrasion resistance
- Aging resistance
- Processing- Set reduction (better load bearing)
- Reduced water swell
- Lower hysteresis
Mechanical Molded Goods
- Increased modulus
- Better heat aging
- Compression set reduction
- Dynamic property improvement
- Reduced swell to polar liquids
- Filler substitution (non-black for black)
Hose
- Improved abrasion on cover
- Better heat aging
- Increased modulus
- Lower compression set
- Improved adhesion to reinforcing elements
Solid Tires
- Improved abrasion
- Lower hysteresis
- Higher modulus
- Improved processing
- Possibly better adhesion
Tires
- Treads for abrasion, hot tear
- Carcass for adhesion and/or filler substitution
- Breaker (belt) stocks for adhesion
Belts
Flat Belts
- Increased abrasion
- Improved reversion resistance
- Reduced cost with clay substitution for black
- Improved cord adhesion
- Increased flex life and modulus
V Belts
- Increased modulus
- Improved abrasion
- Longer flex life
- Improved adhesion to reinforcing elements
Spectrum DetailBack Directory
[Spectrum Detail]

Bis(triethoxysilylpropyl) disulfide(56706-10-6)1HNMR
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