| Identification | Back Directory | [Name]
THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M | [CAS]
5713-61-1 | [Synonyms]
Bromo-2-thienylmagnesium
2-Thienylmagnesium bromide
magnesium,2H-thiophen-2-ide,bromide
THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M
2-Thienylmagnesium bromide solution
thiophen-2-yl-magnesium bromide solution
magnesium bromide thiophen-2-ide (1:1:1)
2-Thienylmagnesium bromide, 1M solution in THF
2-Thienylmagnesium bromide solution 1.0 M in THF
2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal
2-ThienylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal
2-Thienylmagnesium bromide solution, 1.0M in tetrahydrofuran
2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal&trade | [Molecular Formula]
C4H3BrMgS | [MDL Number]
MFCD03094046 | [MOL File]
5713-61-1.mol | [Molecular Weight]
187.341 |
| Chemical Properties | Back Directory | [Boiling point ]
65 °C
| [density ]
1.011 g/mL at 25 °C
| [Fp ]
−6 °F
| [form ]
Solution | [color ]
Yellow to orange to brown | [InChI]
1S/C4H3S.BrH.Mg/c1-2-4-5-3-1;;/h1-3H;1H;/q;;+1/p-1 | [InChIKey]
GSHPYJFNTAMRJF-UHFFFAOYSA-M | [SMILES]
Br[Mg]c1cccs1 |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow to orange to brown liquid | [Uses]
2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:
- 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
- Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
- Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.
| [reaction suitability]
reaction type: Grignard Reaction |
|
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J & K SCIENTIFIC LTD.
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https://www.jkchemical.com |
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Energy Chemical
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www.energy-chemical.com |
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Sigma-Aldrich
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3A Chemicals
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