ChemicalBook--->CAS DataBase List--->898838-07-8

898838-07-8

898838-07-8 Structure

898838-07-8 Structure
IdentificationBack Directory
[Name]

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
[CAS]

898838-07-8
[Synonyms]

piperidinyL
2,2,6,6-tetramethylpiperidin-1-ide
2,2,6,6-Tetramethylpiperidinylmagnesium chloride l
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl
Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride
Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium (1:1)
Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1)
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX
2,2,6,6-Tetramethyl piperidinyl Mag Chloride Lithium Chloride complex 1.M in THF
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX 1.0 M in THF
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 1.0 M solution in THF
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF
2,2,6,6-TetraMethylpiperidinylMagnesiuM chloride lithiuM chloride coMplex solution 1.0 M in THF/toluene
[Molecular Formula]

C9H18Cl2LiMgN
[MDL Number]

MFCD12546030
[MOL File]

898838-07-8.mol
[Molecular Weight]

242.4
Chemical PropertiesBack Directory
[Boiling point ]

66°/759.8mm
[density ]

0.96g/mLat 25℃
[Fp ]

-15°C
[storage temp. ]

2-8°C
[form ]

liquid
[InChI]

InChI=1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2
[InChIKey]

JHBZAAACZVPPRQ-UHFFFAOYSA-L
[SMILES]

[Mg+2]([N-]1C(CCCC1(C)C)(C)C)([Cl-])[Cl-].[Li+]
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H225-H302-H314-H335-H351-H361d
[Precautionary statements ]

P210-P260-P280-P305+P351+P338-P370+P378-P403+P235
[Hazard Codes ]

F,C
[Risk Statements ]

63-11-14-19-34-37-40
[Safety Statements ]

16-26-36/37/39-45
[RIDADR ]

UN 3399 4.3/PG 1
[WGK Germany ]

3
[HazardClass ]

3, 8
[HS Code ]

29333990
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Carc. 2
Eye Dam. 1
Flam. Liq. 2
Repr. 2
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Uses]

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base
[reaction suitability]

reaction type: Grignard Reaction
[Synthesis]

A 1000-ml triple-necked flask was taken, and the reaction flask was replaced three times with argon, and a little argon was turned on after the replacement so that the triple-necked flask was in an argon atmosphere, and then anhydrous lithium chloride (42
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