| Identification | More | [Name]
BRUCINE | [CAS]
5892-11-5 | [Synonyms]
10,11-DIMETHOXYSTRYCHNINE
2,3-DIMETHOXYSTRYCHNIDIN-10-ONE
(-)-BRUCINE
BRUCINE
BRUCINE ALKALOID
BRUCINE TETRAHYDRATE
STRYCHNIDIN-10-ONE,2,3-DIMETHOXY
BRUCINE HYDRATE, TECH.
Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate
BURCINETETRAHYDRATE | [EINECS(EC#)]
206-614-7 | [Molecular Formula]
C23H26N2O4 | [MDL Number]
MFCD00005942 | [Molecular Weight]
394.46 | [MOL File]
5892-11-5.mol |
| Safety Data | Back Directory | [Hazard Codes ]
T+ | [Risk Statements ]
R26/28:Very Toxic by inhalation and if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S13:Keep away from food, drink and animal feeding stuffs .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36/37:Wear suitable protective clothing and gloves .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . | [RIDADR ]
UN 1570 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
EH8925000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
I |
| Hazard Information | Back Directory | [Uses]
Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids. | [Purification Methods]
Crystallise brucine once from water or aqueous Me2CO (as the tetrahydrate), then suspend it in CHCl3 and shake with anhydrous Na2SO4 (to dehydrate the brucine, which then dissolves). Precipitate it by pouring the solution into a large bulk of dry pet ether (b 40-60o), filter and heat to 120o in a high vacuum [Turner J Chem Soc 842 1951]. The tetrahydrate crystallises from a mixture of EtOH and H2O as colourless elongated needles [Eeles Acta Cryst 6 809 1953, Beilstein 27 III/IV 7875.] VERY POISONOUS |
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