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590-14-7

590-14-7 Structure

590-14-7 Structure
IdentificationBack Directory
[Name]

1-BROMO-1-PROPENE
[CAS]

590-14-7
[Synonyms]

1-bromo-propen
1-Bromopropene
1-Brom-1-propen
1-bromo-1-propen
PROPENYL BROMIDE
1-bromopropylene
1-Propenylbromid
Propene, 1-bromo-
1-BROMO-1-PROPENE
1-PROPENYL BROMIDE
1-bromo-prop-1-ene
1-Propene,1-bromo-
1-Propene, 1-bromo-
(1E)-1-Bromo-1-propene
1-Bromo-1-propene 
TRANS-1-BROMO-1-PROPENE
1-Bromo-1-propene,cis+trans
Propenyl bromide (cis-trans)
1-Bromo-1-propene (cis+trans)
1-bromo-1-propene (cis and trans)
1-bromo-1-propene,mixtureofisomers
1-Bromo-1-Propene,MixtureOfIsomers98%
1-Bromo-1-propene,mixtureofcisandtrans
1-Bromo-1-propene (cis- and trans- mixture)
1-BROMO-1-PROPENE, 98%, MIXTURE OF ISOME RS
1-Bromo-1-propene, mixture of cis and trans,98%
1-Bromo-1-propene (cis and trans),1-Propenyl bromide
1-Bromo-1-propene, 95%, mixture of isomers, stabilized
1-Bromo-1-propene, mixture of isomers, stabilized, 95%
1-Bromo-1-propene (cis- and trans- mixture)
1-BroMo-1-propene, Mixture of isoMers, stabilized, 95% 5ML
[EINECS(EC#)]

209-671-6
[Molecular Formula]

C3H5Br
[MDL Number]

MFCD00000186
[MOL File]

590-14-7.mol
[Molecular Weight]

120.98
Chemical PropertiesBack Directory
[Appearance]

clear colourless to yellow liquid
[Melting point ]

−116 °C(lit.)
[Boiling point ]

64-65 °C(lit.)
[density ]

1.420 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.454
[Fp ]

5 °F
[storage temp. ]

2-8°C
[form ]

clear liquid
[color ]

Colorless to Light yellow to Light orange
[BRN ]

1719096
[CAS DataBase Reference]

590-14-7
[EPA Substance Registry System]

1-Propene, 1-bromo- (590-14-7)
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
[Uses]

1-Bromo-1-propene upon n-BuLi treatment generates the propynyllithium anion, in situ, which later undergoes nucleophilic addition reactions. Some of its other applications are:
  • Synthesis of organic reagents such as methyl but-2-ynoate and 1-iodopropyne.
  • Preparation o f intermediates in the total synthesis of (+)-aphanamol I and skyllamycins A-C.
  • Synthesis of allylated pyrazoles, aryl alkynyl sulfides and allenamides.

[Uses]

1-Propenyl bromide is a useful building block, especially when a 3 carbon addition is required, such as its use in the synthesis of the pharmaceutical spilanthol.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 56, p. 4066, 1991 DOI: 10.1021/jo00012a053
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H225-H315-H319-H335
[Precautionary statements ]

P210-P302+P352-P305+P351+P338
[Hazard Codes ]

F,Xi
[Risk Statements ]

11-36/37/38
[Safety Statements ]

26-36
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[RTECS ]

UC7080000
[F ]

8
[TSCA ]

TSCA listed
[HazardClass ]

3.1
[PackingGroup ]

II
[HS Code ]

29033919
Spectrum DetailBack Directory
[Spectrum Detail]

1-BROMO-1-PROPENE(590-14-7)MS
1-BROMO-1-PROPENE(590-14-7)1HNMR
1-BROMO-1-PROPENE(590-14-7)IR1
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