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599-66-6

599-66-6 Structure

599-66-6 Structure
IdentificationBack Directory
[Name]

DI-P-TOLYL SULFONE
[CAS]

599-66-6
[Synonyms]

NSC 208
JACS-599-66-6
P-TOLYL SULFONE
DI-P-TOLYL SULFONE
di-p-tolylsulphone
p,p’-Ditolylsulfone
Sulfone, di-p-tolyl
4,4’-Ditolylsulfone
Bis(4-tolyl)sulfone
Bis(p-tolyl)sulfone
4,4'-Ditolyl sulfone
p,p'-Ditolyl sulfone
Di-p-tolyl sulfone 99%
Di-p-tolyl sulfone, 98+%
Bis(4-methylphenyl)sulfone
Bis(4-methylphenyl) sulfone
4,4'-Dimethyldiphenylsulfone
4,4’-Dimethyldiphenylsulfone
p-Tolyl 4-methylphenyl sulfone
4,4'-Sulfonylbis(methylbenzene)
1,1’-sulfonylbis[4-methyl-benzen
1,1'-Sulfonylbis(4-methylbenzene)
Benzene,1,1’-sulfonylbis[4-methyl-
1-Methyl-4-[(4-methylphenyl)sulfonyl]benzene
[EINECS(EC#)]

209-969-6
[Molecular Formula]

C14H14O2S
[MDL Number]

MFCD00041332
[MOL File]

599-66-6.mol
[Molecular Weight]

246.32
Chemical PropertiesBack Directory
[Melting point ]

158-160 °C(lit.)
[Boiling point ]

359.33°C (rough estimate)
[density ]

1.2052 (rough estimate)
[refractive index ]

1.5200 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

chloroform: soluble25mg/mL, clear, colorless to yellow
[form ]

solid
[Appearance]

White to off-white Solid
[InChI]

1S/C14H14O2S/c1-11-3-7-13(8-4-11)17(15,16)14-9-5-12(2)6-10-14/h3-10H,1-2H3
[InChIKey]

WEAYCYAIVOIUMG-UHFFFAOYSA-N
[SMILES]

Cc1ccc(cc1)S(=O)(=O)c2ccc(C)cc2
[EPA Substance Registry System]

Benzene, 1,1'-sulfonylbis[4-methyl- (599-66-6)
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[TSCA ]

Yes
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

4,4''-Ditolyl Sulfone is used in preparation method of OLED material for improving luminous efficiency.
[Uses]

Di-p-tolyl sulfone may be used in the synthesis of isomeric p-tolylpyridines (α , β and γ ) by photochemical decomposition.
[General Description]

Di-p-tolyl sulfone is a di-p-substituted diaryl sulfone. Its synthesis by the sulfonylation of toluene with p-toluenesulfonic acid (TsOH) in the presence of polystyrene supported aluminium triflate (Ps-Al(OTf)3) catalyst has been reported along with its NMR and IR spectra. The gas-phase heats of formation of di-p-tolyl sulfone has been studied. The kinetics and thermodynamics of sulphuric acid assisted cleavage of di-p-tolyl sulfone has been invesitigated.
[Purification Methods]

Crystallise the sulfone repeatedly from Et2O or EtOH. It has been purified by zone melting. [Beilstein 6 H 419, 6 II 395, 6 III 1405, 6 IV 2174.]
Spectrum DetailBack Directory
[Spectrum Detail]

DI-P-TOLYL SULFONE(599-66-6)1HNMR
DI-P-TOLYL SULFONE(599-66-6)Raman
DI-P-TOLYL SULFONE(599-66-6)IR
DI-P-TOLYL SULFONE(599-66-6)FT-IR
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