| Identification | More | [Name]
PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE | [CAS]
6048-29-9 | [Synonyms]
BENZOYLMETHYLTRIPHENYLPHOSPHONIUM BROMIDE
PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE
phenacyltriphenyl-phosphoniubromide
PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE, TE CH., 90+%
Phenacyl triphenylphosphonium bromide, 98+%
Phenacyltriphenylphosphonium bromide, 96 %
(Benzoylmethyl)triphenylphosphonium bromide, 98+%
PHENACYLTRIPHENYLPHOSPHONIUM BROMIDE 96% | [EINECS(EC#)]
227-945-3 | [Molecular Formula]
C26H22BrOP | [MDL Number]
MFCD00011920 | [Molecular Weight]
461.33 | [MOL File]
6048-29-9.mol |
| Chemical Properties | Back Directory | [Appearance]
LIGHT BEIGE AMORPHOUS POWDER | [Melting point ]
265-268 °C (dec.) (lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
very faint turbidity in Methanol | [form ]
solid | [color ]
White to Light yellow to Light orange | [Sensitive ]
Hygroscopic | [BRN ]
3642554 | [InChI]
1S/C26H22OP.BrH/c27-26(22-13-5-1-6-14-22)21-28(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1 | [InChIKey]
AEHDSYHVTDJGDN-UHFFFAOYSA-M | [SMILES]
[Br-].O=C(C[P+](c1ccccc1)(c2ccccc2)c3ccccc3)c4ccccc4 | [CAS DataBase Reference]
6048-29-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
TA2400000
| [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
LIGHT BEIGE AMORPHOUS POWDER | [Uses]
Catalyst for protections and deprotection of alcohols via etherification
Reactant involved in:
- Investigations of gas-phase pyrolysis
- Asymmetric hydroxylamine / enone cascade reactions
- Reductive Michael cyclizations
- Microwave-assisted Wittig olefination
- Synthesis of polyfunctionally substituted heterocycles
| [reaction suitability]
reaction type: C-C Bond Formation |
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