| Identification | More | [Name]
1-PHENYLNAPHTHALENE | [CAS]
605-02-7 | [Synonyms]
1-PHENYLNAPHTHALENE
1-Phenylnaphthalene,97%
1-naphthylbenzene
α-Phenylnaphthalene | [EINECS(EC#)]
210-081-6 | [Molecular Formula]
C16H12 | [MDL Number]
MFCD00003983 | [Molecular Weight]
204.27 | [MOL File]
605-02-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to yellow viscous liquid | [Melting point ]
45°C | [Boiling point ]
324-325 °C (lit.) | [density ]
1.085 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.664(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
clear liquid | [color ]
Light orange to Yellow to Green | [BRN ]
1906885 | [InChI]
1S/C16H12/c1-2-7-13(8-3-1)16-12-6-10-14-9-4-5-11-15(14)16/h1-12H | [InChIKey]
IYDMICQAKLQHLA-UHFFFAOYSA-N | [SMILES]
c1ccc(cc1)-c2cccc3ccccc23 | [CAS DataBase Reference]
605-02-7(CAS DataBase Reference) | [EPA Substance Registry System]
1-Phenylnaphthalene (605-02-7) |
| Questions And Answer | Back Directory | [Synthesis]
To a suspension of potassium phenyltriflfluoroborate (92.3 mg, 0.5 mmol), 1-bromonapthalene (103.5 mg, 0.5 mmol), and K2CO3 (204.5 mg, 1. 5 mmol) in MeOH (0.75 mL) was added Pd(OAc)2 in methanol (1.25 mL, 2 × 10–3 M) and then the reaction mixture was stirred and heated at reflflux for 2 h. The mixture was cooled to room temperature and diluted with water (10 mL). The aqueous phase was extracted with CH2Cl2 (3 × 4 mL). The combined organic extracts were washed with brine (10 mL) and dried (MgSO4). The crude product was then purifified via chromatography (silica gel) eluting with hexane to deliver 76.1 mg (75%) of 1-phenylnaphthalene. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.
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| Safety Data | Back Directory | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [HS Code ]
2902.90.9000 | [Storage Class]
10 - Combustible liquids |
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