| Identification | Back Directory | [Name]
3-HYDROXY-PHENANTHRENE | [CAS]
605-87-8 | [Synonyms]
NSC 30984
3-Phenanthrol
3-Phenanthrenol
3-HYDROXY-PHENANTHRENE | [Molecular Formula]
C14H10O | [MDL Number]
MFCD00215969 | [MOL File]
605-87-8.mol | [Molecular Weight]
194.23 |
| Chemical Properties | Back Directory | [Appearance]
Tan Solid | [Melting point ]
92-94°C | [Boiling point ]
404.5±14.0 °C(Predicted) | [density ]
1.244±0.06 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
9.57±0.30(Predicted) | [color ]
Pale Red to Pale Brown | [InChI]
InChI=1S/C14H10O/c15-12-8-7-11-6-5-10-3-1-2-4-13(10)14(11)9-12/h1-9,15H | [InChIKey]
NGPOABOEXMDQBT-UHFFFAOYSA-N | [SMILES]
C1=C2C(C3C(C=C2)=CC=CC=3)=CC(O)=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
Tan Solid | [Uses]
A metabolite of Phenanthrene | [Application]
In a mixed solvent of water-acetic acid-propionic acid, 3-phenanthrol was nitrated with an equimolar amount of nitric acid at - 25 - 20°C to obtain a mixture of mononitro compounds containing a small amount of polynitro compounds. The mixture consisted of 9-nitro-3-phenanthrol, 4-nitro-3-phenanthrol, and 2-nitro -3-phenanthrol, the amount of each product being decreased in this order. Further nitration of 4-nitro-3-phenanthrol and 2-nitro -3-phenanthrol in dilute acetic acid at 1112°C gave a common product, 4, 9-dinitro-3-phenanthrol[1].
| [Definition]
ChEBI: 3-phenanthrol is a phenanthrol. | [References]
[1] E. ōta, K. Iwamoto, H. Kawashima. “Nitration of 3-Phenanthrol.” Journal of Synthetic Organic Chemistry Japan 22 1 (1969): 157–161.
|
|
|