| Identification | More | [Name]
2-IODOBENZOYL CHLORIDE | [CAS]
609-67-6 | [Synonyms]
2-IODOBENZOYL CHLORIDE
O-IODOBENZOYL CHLORIDE
2-iodo-benzoylchlorid
Benzoyl chloride, 2-iodo-
2-Iodobenzoylchloride,97%
2-Iodobenzoyl chloride, 98+%
2-Iodobenzoic acid chloride | [EINECS(EC#)]
210-196-1 | [Molecular Formula]
C7H4ClIO | [MDL Number]
MFCD00001040 | [Molecular Weight]
266.46 | [MOL File]
609-67-6.mol |
| Chemical Properties | Back Directory | [Appearance]
white to pinkish or pale yellow crystalline | [Melting point ]
27-31 °C(lit.) | [Boiling point ]
105-106 °C1 mm Hg(lit.) | [density ]
1.932 | [Fp ]
>110°C | [storage temp. ]
Keep in dark place,Inert atmosphere,2-8°C | [solubility ]
soluble in Toluene | [form ]
powder to lump | [color ]
White to Light yellow to Dark green | [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture & Light Sensitive | [BRN ]
2042672 | [InChIKey]
MVIVDSWUOGNODP-UHFFFAOYSA-N | [CAS DataBase Reference]
609-67-6(CAS DataBase Reference) | [EPA Substance Registry System]
Benzoyl chloride, 2-iodo- (609-67-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
21-19 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29163990 |
| Hazard Information | Back Directory | [Chemical Properties]
white to pinkish or pale yellow crystalline | [Uses]
2-Iodobenzoyl chloride has been used in:
- palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones
- preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides
| [Uses]
2-Iodobenzoyl chloride has been used in palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones, preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides. | [Synthesis]
General method: 2-iodobenzoic acid (1.0 mmol) was mixed with excess thionyl chloride (5 mL) and reacted at reflux for 2 hours. Upon completion of the reaction, the excess thionyl chloride was removed by vacuum concentration to give o-iodobenzoyl chloride in quantitative yield. | [References]
[1] Journal of Medicinal Chemistry, 1994, vol. 37, # 12, p. 1737 - 1739
[2] Chinese Chemical Letters, 2013, vol. 24, # 8, p. 673 - 676
[3] Patent: WO2015/137750, 2015, A1. Location in patent: Paragraph 1245; 1246
[4] Organometallics, 2013, vol. 32, # 11, p. 3220 - 3226
[5] Synlett, 1999, # 11, p. 1763 - 1765 |
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