ChemicalBook--->CAS DataBase List--->6290-17-1

6290-17-1

6290-17-1 Structure

6290-17-1 Structure
IdentificationMore
[Name]

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL
[CAS]

6290-17-1
[Synonyms]

ETHYL-2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE
ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL
ETHYL DIMETHYL DIOXOLANE ACETATE
FRAISTONE
1,3-Dioxolane-2-aceticacid,2,4-dimethyl-,ethylester
3-dioxolane-2-aceticacid,2,4-dimethyl-ethylester
Acetoaceticacid,ethylester,1,2-propyleneketal
2,4-Dimethyl-1,3-dioxolane-2-acetic acid ethyl ester~Ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate
Ethyl actoacetate propyleneglycol ketal
2,4-dimethyl-1,3-dioxolane-2-acetic acid ethyl ester
[EINECS(EC#)]

228-536-2
[Molecular Formula]

C9H16O4
[MDL Number]

MFCD00151819
[Molecular Weight]

188.22
[MOL File]

6290-17-1.mol
Chemical PropertiesBack Directory
[Boiling point ]

90°C 10mm
[density ]

1.042 g/mL at 25 °C(lit.)
[vapor pressure ]

7.9Pa at 24℃
[FEMA ]

4294 | CIS- AND TRANS-ETHYL 2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE
[refractive index ]

1.4280
[Fp ]

65°C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[Odor]

at 100.00 %. fresh fruity apple strawberry licorice
[Odor Type]

fruity
[Water Solubility ]

1.244g/L at 24℃
[JECFA Number]

1715
[BRN ]

138927
[Cosmetics Ingredients Functions]

PERFUMING
[LogP]

1.8 at 25℃
[CAS DataBase Reference]

6290-17-1(CAS DataBase Reference)
[EPA Substance Registry System]

1,3-Dioxolane-2-acetic acid, 2,4-dimethyl-, ethyl ester (6290-17-1)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Flame (GHS02)
GHS07,GHS02
[Signal word ]

Warning
[Hazard statements ]

H227
[Precautionary statements ]

P210e-P280a-P370+P378a-P403+P235-P501a
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

2932990090
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid; soft, fruity notes.
[Chemical Properties]

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL is a colorless liquid with a fresh, fruity odor reminiscent of apples and strawberries. It is mainly used to create fresh, fruity top notes to floral fragrances.
Thematerial is available by reaction of ethyl acetoacetate with propane-1,2-diol.
[Physical properties]

Colorless or pale straw-colored oily liquid. Insoluble in water, soluble in alcohol, miscible with oils.
[Uses]

Ethyl acetoacetate propylene glycol ketal is a ketal derivative used in the synthesis of fragrances.
[Definition]

ChEBI: Cis- and trans-Ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate is a fatty acid ester.
[Production Methods]

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL can be produced from Propylene glycol and Ethyl acetoacetate. The latter acts as a ketone to condense with the glycol. The condcnsat ion is normally encouraged by a catalyst and carried out under conditions of azeotropic distillation.
[Aroma threshold values]

Medium strength odor, fruity type.
[Trade name]

Fraistone (IFF), Fragolane (Symrise)
Questions And AnswerBack Directory
[Aroma]

Fruity-floral and warm, sweet odor of good tenacity. The wincy-"fermented-fruit-like" undertones resemble the odor of Strawberry preserve.
[Uses in Perfume]

ETHYL ACETOACETATE PROPYLENE GLYCOL KETAL has found some use in perfume compositions where a certain deep-fruity note is desirable along with a floral complex. Jasmin, Tuberose, Gardenia and many other floral bases, spicy fragrances, etc. can achieve new and interesting "lifts" from this material, which has an overall effect resembling that of the alkyl-substituted Cyclopentenones and their homoiogues.
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Ethyl acetoacetate propylene glycol ketal, 97%(6290-17-1)
[Sigma Aldrich]

6290-17-1(sigmaaldrich)
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