| Identification | Back Directory | [Name]
ADOGEN(R) 464 | [CAS]
63393-96-4 | [Synonyms]
336
TOM-ACL
ADOGEN 464
aliquat 128
Aliquat336s
aliquat7402
aliquatn263
disperstata
disperstatw
Aliquat®
ADOGEN(R) 464
Tricaprylylmethylammonium ch]
Aliquat(R) 336,average MW 442
A 1 (phase transfer catalyst)
Aliquat 336, average MW 442 1LT
Trialkylmethylammonium chloride
Methyltrialkylammonium chloride
(R=C8-C10) [Phase-transfer Catalyst]
TrioctylMethylaMMoniuM Chloride
Methyl mixed trialkylammonium chloride
Tridecyl alkyl methyl ammonium chloride
METHYLTRIALKYL(C8-C10)AMMONIUM CHLORIDE
METHYLTRIOCTYLAMMONIUM CHLORIDE FOR SYNT
MethyltrioctylaMMoniuM chloride (R=C8-C10)
TricaprylylMethylaMMoniuM chloride(R=C8-C10)
Three decyl alkyl dimethyl ammonium chloride
Tricaprylmethylammonium chloride [average MW 442]
Tri-C8-10-alkylmethylammonium chlorides
Tricaprylylmethylammonium chloride[Phase-transfer Catalyst]
quaternaryammoniumcompounds,tri-c8-10-alkylmethyl,chlorides
Quaternaryammoniumcompounds,tri-C8-10-alkylmethyl-,chlorides
tri-c(sub8-10)-alkylmethyl-quaternaryammoniumcompoundchlorides
Methyltrioctylammonium Chloride
Tricaprylmethylammonium Chloride
Tricaprylylmethylammonium chloride mixture of C8-C10 C8 is dominant
TrioctylMethylaMMoniuM Chloride (R=C8-C10) [Phase-transfer Catalyst]
Tricaprylylmethylammonium chloride, Trioctylmethylammonium chloride
Aliquat 336,Tricaprylylmethylammonium chloride, Trioctylmethylammonium chloride
Aliquat 336: (Adogen 464: Quaternary ammonium compounds, tri(C8-10)-alkylmethyl-, chlorides) | [EINECS(EC#)]
264-120-7 | [Molecular Formula]
CH3N[(CH2)7CH3]3Cl | [MDL Number]
MFCD00132827 | [MOL File]
63393-96-4.mol | [Molecular Weight]
404.156 |
| Chemical Properties | Back Directory | [Appearance]
Viscous liquid | [Boiling point ]
>240℃ | [density ]
0.898 g/mL at 25 °C(lit.)
| [vapor density ]
>1 (vs air)
| [vapor pressure ]
33 mm Hg ( 20 °C)
| [refractive index ]
n20/D 1.4665(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Store below +30°C. | [solubility ]
Miscible with benzene and chloroform. | [form ]
Viscous Liquid | [color ]
Amber | [Water Solubility ]
1.023g/L at 20℃ | [Sensitive ]
Hygroscopic | [InChI]
InChI=1S/C25H54N.ClH/c1-5-8-11-14-17-20-23-26(4,24-21-18-15-12-9-6-2)25-22-19-16-13-10-7-3;/h5-25H2,1-4H3;1H/q+1;/p-1 | [InChIKey]
XKBGEWXEAPTVCK-UHFFFAOYSA-M | [SMILES]
[N+](C)(CCCCCCCC)(CCCCCCCC)CCCCCCCC.[Cl-] | [LogP]
2.93 at 25℃ | [EPA Substance Registry System]
Quaternary ammonium compounds, tri-C8-10-alkylmethyl, chlorides (63393-96-4) |
| Hazard Information | Back Directory | [Chemical Properties]
amber viscous liquid at room temperature | [Uses]
Quat suitable for nearly all PTC applications without aqueous work-up | [Uses]
Aliquat 336 is widely utilized as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. It is involved in the total synthesis of Manzamine A. It serves as an anti-static agent for textile fabrics and carpeting. It finds application in waste water treatment to control foaming. It has a major application as a metal extraction reagent for cadmium, zinc, iron and rare earth metals. It is used as an effective catalyst for the preparation of methylphenyl ether from sodium phenolate with for methyl bromide. | [Definition]
ChEBI: Methyltrioctylammonium chloride is an organic chloride salt having methyltrioctylammonium as the cation. It has a role as a phase-transfer catalyst. It is a quaternary ammonium salt and an organic chloride salt. It contains a methyltrioctylammonium. | [Flammability and Explosibility]
Notclassified | [Purification Methods]
A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.] |
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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Maya High Purity Chemicals
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