| Identification | More | [Name]
TERT-BUTYL ETHYL ETHER | [CAS]
637-92-3 | [Synonyms]
ETBE
ETHYL-TERT-BUTYL ETHER
ETHYL TERTIARY BUTYL ETHER
T-BUTYLETHYL ETHER
TERT-BUTYL ETHYL ETHER
1,1-dimethylethylethylether
2-ethoxy-2-methyl-propan
2-Ethoxy-2-methylpropane
2-ethoxy-2-methyl-propane
2-methyl-2-ethoxypropane
Ether, tert-butyl ethyl
ether,tert-butylethyl
Ethyl tert-butyl oxide
ethyl(2-methyl-2-propyl)ether
ethyl1,1-dimethylethylether
ethyltert-butyloxide
Propane,2-ethoxy-2-methyl-
tert-C4H9OC2H5
TERT-BUTYL ETHYL ETHER, 1000MG, NEAT
tert-Butylethylether,97% | [EINECS(EC#)]
211-309-7 | [Molecular Formula]
C6H14O | [MDL Number]
MFCD00009225 | [Molecular Weight]
102.17 | [MOL File]
637-92-3.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless to light yellow liquid | [Melting point ]
−97 °C(lit.) | [Boiling point ]
72-73 °C(lit.) | [density ]
0.742 g/mL at 25 °C(lit.)
| [vapor pressure ]
155 mm Hg ( 25 °C)
| [refractive index ]
n20/D 1.375(lit.)
| [Fp ]
-19 °C
| [storage temp. ]
Flammables area | [solubility ]
water: soluble1.2 g/100g at 20°C(lit.) | [form ]
Powder/Solid | [color ]
White | [Stability:]
Stable, but may react with air to form peroxides. Once opened, store under an inert atmosphere and test for the presence of peroxides before use. Highly flammable. Incompatible with strong oxidizing agents. | [explosive limit]
1.23-7.7%(V) | [Water Solubility ]
Miscible with alcohol, ethyl ether. Slightly miscible with water. | [Merck ]
14,3774 | [BRN ]
1731469 | [Exposure limits]
ACGIH: TWA 25 ppm | [InChIKey]
NUMQCACRALPSHD-UHFFFAOYSA-N | [CAS DataBase Reference]
637-92-3(CAS DataBase Reference) | [EPA Substance Registry System]
Ethyl tert-butyl ether (637-92-3) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 1179 3/PG 2
| [WGK Germany ]
1
| [RTECS ]
KN4730200
| [F ]
23 | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29091990 | [Hazardous Substances Data]
637-92-3(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
Clear light yellow liquid. | [Reactivity Profile]
2-METHYL-2-ETHOXYPROPANE(637-92-3) can act as a base to form salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. Relatively inert in other reactions, which typically involve the breaking of the carbon-oxygen bond. | [Air & Water Reactions]
Highly flammable. This chemical may react with air to form dangerous peroxides. . Insoluble in water. | [Health Hazard]
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
This chemical is flammable. | [Description]
In the 1990s, the production of other fuel oxygenates began,
with the appearance of ethyl tertiary-butyl ether, CAS RN 637-
92-3 (ETBE), first produced in France in 1992, and tertiary-amyl
methyl ether, CAS RN 994-05-8 (TAME). To their number
others have been added, such as diisopropyl ether, CAS RN
108-20-3 (DIPE) and, most recently, tertiary-amyl ethyl ether,
CAS RN 919-94-8 (TAEE), which is being produced in
Germany; however, the use of these oxygenates is currently
small scale. Alcohols, such as ethanol, CAS RN 64-17-5 (EtOH)
and methanol, may also be used as fuel oxygenates, but
methanol is not used as such, although it is used in China as
a liquid fuel for passenger cars and for synthesis of dimethyl
ether as an alternative to diesel fuel for trucks and buses. Ethers
have the advantage over alcohols in currently designed engines
because alcohols in petrol tend to make the blend very volatile
and water soluble, possibly creating problems in the fueldistribution
system and vehicle engine. Perhaps the larger-scale
use of ethanol in fuel oxygenation is in the production of ETBE
or coblending with ETBE. | [Chemical Properties]
tert-Butyl ethyl ether is a colourless to light yellow liquid at a temperature range of -94 to 72.6 °C. It is soluble in ethanol, ethyl ether, and water. tert-Butyl ethyl ether has a strong, highly objectionable odor and taste at relatively low concentrations. This chemical is highly flammable and reacts with strong oxidizing agents. tert-Butyl ethyl ether is stable when stored at room temperature in tightly closed containers. | [Uses]
Gasoline additive. tert-Butyl ethyl ether is synthesized from ethanol and isobutene and is used primarily as an oxygenate that is added to gasoline to improve the automobile exhaust quality by reducing the ozone and carbon monoxide emissions (HSDB, 2012). tert-Butyl ethyl ether has similar utility compared to another widely used oxygenate, methyl tertiary butyl ether (MTBE), and thus is a potential replacement for MTBE.Usage of ETBE as a fuel additive has halted in the United States, falling from 2 to 4 million barrels per month in 2005 to 0 barrels in 2006 (DOE, 2007). tert-Butyl ethyl ether continues to be used widely in Europe (EFOA, 2010). Since ETBE is used almost exclusively in fuels, contamination of groundwater as a result of spillage or leakage of the underground storage tanks is a major source of environmental release. | [Uses]
In 2006, because of litigation and liability fears, the
blending (but not the production) of MTBE into petrol in the
United States was discontinued, whereas the European Union
(EU) has continued its use of ethers in blending. Other global
producers and consumers of fuel ether oxygenates are the
Middle East, South America (excluding Brazil), Mexico, and
a large portion of Asia. The current global production capacity
is estimated to be approximately 18 Mton year1. The expected
demand for MTBE t ETBE in Asia is 11.9 Mton. In 2010, China
was the world’s largest producer of MTBE (6.8 Mton year1),
yet was also importing MTBE at 740 kton in the same year. In
Japan, Bio-ETBE is the biofuel of choice for petrol. It is preferred
over alcohols in Japan on the basis of emission benefits, vehicle
performance, and existing regulations. | [Uses]
tert-Butyl ethyl ether is used as an oxygenate gasoline additive oxygenate during its production from crude oil. It is used as an extractant in human urine by using single-walled carbon nanotubes as an adsorbent. It plays an important role as a fuel component in petrol to enhance its octane rating. | [Definition]
ChEBI: Tert-butyl ethyl ether is an ether having ethyl and tert-butyl as the two alkyl components. It is used as an engine fuel additive to reduce emissions of carbon monoxide and soot. It has a role as a fuel additive. It is an ether and a volatile organic compound. | [Synthesis Reference(s)]
Tetrahedron Letters, 29, p. 2445, 1988 DOI: 10.1016/S0040-4039(00)87903-4 | [Flammability and Explosibility]
Highlyflammable | [Environmental Fate]
Due to the usage of Ethyl tertiary butyl ether (ETBE ) as a fuel additive, ETBE may be released into air, soil, and water. Ethyl tertiary butyl ether will exist as a vapor at 25 °C due to its vapor pressure of 124mmHg and is estimated to have a half-life of 2 days. Upon release into the soil, ETBE is anticipated to have a high mobility based on the high soil organic carbon–water partitioning coefficient of 9–160. Once in the water, ETBE is not predicted to adsorb onto suspended particles and is likely to resist biodegradation (Deeb et al., 2001). Based on the Henry’s law constant, ETBE is likely to be volatized from the surface of the water (HSDB, 2012). A volatilization halflife of 3 h to 4 days is anticipated from water solutions. A bioconcentration factor (BCF) of 9 was estimated for ETBE to accumulate in fish, suggesting a relatively low propensity for aquatic bioaccumulation (HSDB, 2012). | [Purification Methods]
Dry the ether with CaSO4, pass it through an alumina column, and fractionally distil it. [Beilstein 1 IV 1618.] |
|
|